PUMA publications for /user/galaktoze/platinum%20structure%20complex%20mononuclearhttps://puma.ub.uni-stuttgart.de/user/galaktoze/platinum%20structure%20complex%20mononuclearPUMA RSS feed for /user/galaktoze/platinum%20structure%20complex%20mononuclear2024-03-29T12:16:35+01:00Complexes of 1,3-bis(diphenylphosphino)propane (dppp) with dichloroplatinum(II) and bis(chlorogold(I)): Intramolecular versus intermolecular AuI-AuI association of (m-dppp)(AuCl)2 in catena and cyclo formshttps://puma.ub.uni-stuttgart.de/bibtex/2fa9a57a1d793755312336dd70a70f686/galaktozegalaktoze2018-08-09T10:59:25+02:00chloro complex complex;propanediphosphine crystal dinuclear gold mononuclear platinum prepn propanediphosphine structure <span data-person-type="author" class="authorEditorList "><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Wolfgang Kaim" itemprop="url" href="/person/169571bc4c025c94cdd87d819e4b13a4f/author/0"><span itemprop="name">W. Kaim</span></a></span>, </span><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Akbey Dogan" itemprop="url" href="/person/169571bc4c025c94cdd87d819e4b13a4f/author/1"><span itemprop="name">A. Dogan</span></a></span>, </span><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Axel Klein" itemprop="url" href="/person/169571bc4c025c94cdd87d819e4b13a4f/author/2"><span itemprop="name">A. Klein</span></a></span>, </span> und <span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Stanislav. Zalis" itemprop="url" href="/person/169571bc4c025c94cdd87d819e4b13a4f/author/3"><span itemprop="name">S. Zalis</span></a></span></span>. </span><span class="additional-entrytype-information"><span itemtype="http://schema.org/PublicationIssue" itemscope="itemscope" itemprop="isPartOf"><em><span itemprop="journal">Zeitschrift fuer Anorganische und Allgemeine Chemie</span>, </em> <em><span itemtype="http://schema.org/PublicationVolume" itemscope="itemscope" itemprop="isPartOf"><span itemprop="volumeNumber">631 </span></span>(<span itemprop="issueNumber">8</span>):
<span itemprop="pagination">1355--1358</span></em> </span>(<em><span>2005<meta content="2005" itemprop="datePublished"/></span></em>)</span>Thu Aug 09 10:59:25 CEST 2018Zeitschrift fuer Anorganische und Allgemeine Chemie81355--1358Complexes of 1,3-bis(diphenylphosphino)propane (dppp) with dichloroplatinum(II) and bis(chlorogold(I)): Intramolecular versus intermolecular AuI-AuI association of [(\textgreek{m}-dppp)(AuCl)2] in catena and cyclo forms6312005chloro complex complex;propanediphosphine crystal dinuclear gold mononuclear platinum prepn propanediphosphine structure [(\textgreek{m}-Dppp)(AuCl)2], previously reported to assoc. intermolecularly in a chain (catena) structure through Au1-Au1 interactions (3.316 {\AA}), was obtained from gold(III) precursors in a cyclo form with shortened intramol. AuI-AuI contacts at 3.237 {\AA} and a puckered AuPCCCPAu seven-membered ring. DFT calcns. using a large relativistic basis to account for the d10-d10 interaction reproduce the obsd. mol. structure in the crystal of this linkage isomer, including the conspicuous distortion at one of the gold atoms. The chelate complex [(dppp)PtCl2] was crystd. and structurally characterized as the dichloromethane solvate. [on SciFinder(R)]