PUMA publications for /user/b_schwederski/platinum;electrochemhttps://puma.ub.uni-stuttgart.de/user/b_schwederski/platinum;electrochemPUMA RSS feed for /user/b_schwederski/platinum;electrochem2024-03-28T16:15:19+01:00protection of the axial positions of square-planar platinum(II) center of (2,2'-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III)https://puma.ub.uni-stuttgart.de/bibtex/237fcb3b3a8bff55a38a1d9d7dab5b7e0/b_schwederskib_schwederski2019-07-15T13:41:23+02:00bipyridine crystal dimesityl platinum platinum;Luminescence platinum;electrochem platinum;mol redox structure <span data-person-type="author" class="authorEditorList "><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Axel Klein" itemprop="url" href="/person/19f53bc37fa0fd06956ebd5a46ba6a13b/author/0"><span itemprop="name">A. Klein</span></a></span>, </span><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Hans-Dieter Hausen" itemprop="url" href="/person/19f53bc37fa0fd06956ebd5a46ba6a13b/author/1"><span itemprop="name">H. Hausen</span></a></span>, </span> and <span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Wolfgang. Kaim" itemprop="url" href="/person/19f53bc37fa0fd06956ebd5a46ba6a13b/author/2"><span itemprop="name">W. Kaim</span></a></span></span>. </span><span class="additional-entrytype-information"><span itemtype="http://schema.org/PublicationIssue" itemscope="itemscope" itemprop="isPartOf"><em><span itemprop="journal">Journal of Organometallic Chemistry</span>, </em> <em><span itemtype="http://schema.org/PublicationVolume" itemscope="itemscope" itemprop="isPartOf"><span itemprop="volumeNumber">440 </span></span>(<span itemprop="issueNumber">1-2</span>):
<span itemprop="pagination">207--217</span></em> </span>(<em><span>1992<meta content="1992" itemprop="datePublished"/></span></em>)</span>Mon Jul 15 13:41:23 CEST 2019Journal of Organometallic Chemistry1-2207--217protection of the axial positions of square-planar platinum(II) center of (2,2'-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III)4401992bipyridine crystal dimesityl platinum platinum;Luminescence platinum;electrochem platinum;mol redox structure The mol. structure of (2,2'-bipyridine)dimesitylplatinum as detd. by x-ray diffraction reveals efficient protection of the axial positions of the essentially square-planar platinum(II) center. The chem. consequences include a strongly diminished propensity towards oxidative addn. and the electrochem. reversible oxidn. at about +0.4 V vs. Fc/Fc+ to a reactive Pt(III) cation. In conjunction with the MLCT absorption and emission energies and the potential for reversible redn. to an anion radical complex, the contributions from intra- and intermol. reorganization could be reliably detd. [on SciFinder(R)]