PUMA publications for /user/b_schwederski/hyperfine%20triethylhydridoborate;triplehttps://puma.ub.uni-stuttgart.de/user/b_schwederski/hyperfine%20triethylhydridoborate;triplePUMA RSS feed for /user/b_schwederski/hyperfine%20triethylhydridoborate;triple2024-03-28T21:18:16+01:00Radical products in single electron transfer reactions of lithium triethylhydridoborate as detected by ESR and multinuclear (proton, boron-10, boron-11, and nitrogen-14) ENDOR spectroscopyhttps://puma.ub.uni-stuttgart.de/bibtex/2da76a517940dfff259fabfe06ef07e4a/b_schwederskib_schwederski2019-07-15T13:41:23+02:00ENDOR;electron bipyridine bipyridine;ENDOR bipyridine;boron borohydride complex coupling electron hyperfine lithium transfer triethyl triethylhydridoborate triethylhydridoborate;ESR triethylhydridoborate;TRIPLE <span data-person-type="author" class="authorEditorList "><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Wolfgang Kaim" itemprop="url" href="/person/1bd11fb67bf9865898b89abb4db5a2e25/author/0"><span itemprop="name">W. Kaim</span></a></span>, </span> and <span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Wolfgang. Lubitz" itemprop="url" href="/person/1bd11fb67bf9865898b89abb4db5a2e25/author/1"><span itemprop="name">W. Lubitz</span></a></span></span>. </span><span class="additional-entrytype-information"><span itemtype="http://schema.org/PublicationIssue" itemscope="itemscope" itemprop="isPartOf"><em><span itemprop="journal">Angewandte Chemie</span>, </em> <em><span itemtype="http://schema.org/PublicationVolume" itemscope="itemscope" itemprop="isPartOf"><span itemprop="volumeNumber">95 </span></span>(<span itemprop="issueNumber">11</span>):
<span itemprop="pagination">915--916</span></em> </span>(<em><span>1983<meta content="1983" itemprop="datePublished"/></span></em>)</span>Mon Jul 15 13:41:23 CEST 2019Angewandte Chemie11915--916Radical products in single electron transfer reactions of lithium triethylhydridoborate as detected by ESR and multinuclear (proton, boron-10, boron-11, and nitrogen-14) ENDOR spectroscopy951983ENDOR;electron bipyridine bipyridine;ENDOR bipyridine;boron borohydride complex coupling electron hyperfine lithium transfer triethyl triethylhydridoborate triethylhydridoborate;ESR triethylhydridoborate;TRIPLE LiBHEt3 reacted with 4,4'-bipyridine (I) to give [I.2BEt3].bul.- and with 2,2'-bipyridine (II) to give [II.Li].bul., as shown by ESR. Hyperfine couplings in these complexes and in a pyrazine (III) complex, [III.2BEt3].bul.- were detd. by the ENDOR/TRIPLE method. Gross information about dipolar and quadrupolar interactions can also be obtained from temp.-dependent ENDOR intensities and linewidths. ENDOR resonance from 10B and 11B were detected for the 1st time because of their favorable relaxation behavior in these systems. [on SciFinder(R)]