PUMA publications for /user/b_schwederski/basicity;crystalhttps://puma.ub.uni-stuttgart.de/user/b_schwederski/basicity;crystalPUMA RSS feed for /user/b_schwederski/basicity;crystal2024-03-28T20:56:15+01:00Lewis basicity of a chlorine atom bound to an aliphatic carbon atom as sensed by a quadruple chromium-chromium bond. Structures of M2(2,6-xylyl)NC(CH3)O4.2CH2Cl2, M = chromium, molybdenumhttps://puma.ub.uni-stuttgart.de/bibtex/26858dd642044e820e176a9141a807b58/b_schwederskib_schwederski2019-07-15T13:41:23+02:00basicity;crystal bond chlorine chromium length quadruple structure <span data-person-type="author" class="authorEditorList "><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="F. Albert Cotton" itemprop="url" href="/person/1f1c0c3ca67506148022161e9b03fc182/author/0"><span itemprop="name">F. Cotton</span></a></span>, </span><span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="William H. Ilsley" itemprop="url" href="/person/1f1c0c3ca67506148022161e9b03fc182/author/1"><span itemprop="name">W. Ilsley</span></a></span>, </span> and <span><span itemtype="http://schema.org/Person" itemscope="itemscope" itemprop="author"><a title="Wolfgang. Kaim" itemprop="url" href="/person/1f1c0c3ca67506148022161e9b03fc182/author/2"><span itemprop="name">W. Kaim</span></a></span></span>. </span><span class="additional-entrytype-information"><span itemtype="http://schema.org/PublicationIssue" itemscope="itemscope" itemprop="isPartOf"><em><span itemprop="journal">Journal of the American Chemical Society</span>, </em> <em><span itemtype="http://schema.org/PublicationVolume" itemscope="itemscope" itemprop="isPartOf"><span itemprop="volumeNumber">102 </span></span>(<span itemprop="issueNumber">10</span>):
<span itemprop="pagination">3475--3479</span></em> </span>(<em><span>1980<meta content="1980" itemprop="datePublished"/></span></em>)</span>Mon Jul 15 13:41:23 CEST 2019Journal of the American Chemical Society103475--3479Lewis basicity of a chlorine atom bound to an aliphatic carbon atom as sensed by a quadruple chromium-chromium bond. Structures of M2[(2,6-xylyl)NC(CH3)O]4.2CH2Cl2, M = chromium, molybdenum1021980basicity;crystal bond chlorine chromium length quadruple structure The length of the quadruple bond between two Cr atoms is an extremely sensitive function of the amt. of \textgreek{s} electron d. donated to one or both of the C-atoms along the outer extensions of the Cr-Cr bond. In I (R = 2,6-xylyl, M = Cr, L = CH2Cl2) one Cr atom causes the Cr-Cr distance to become 0.076 (9) {\AA} longer than it is in the absence of this weak axial Cl···Cr interaction. The crystal structures of the isomorphous I (R = 2,6-xylyl, M = Cr, Mo, L = CH2Cl2) are reported. [on SciFinder(R)]