%0 Journal Article %1 Kaim.1982b %A Kaim, Wolfgang %A Haenel, Peter %A Lechner-Knoblauch, Ulrike %A Bock, Hans. %D 1982 %J Chemische Berichte %K anion anion;phosphine anion;radical aryldimethyl aryldimethylphosphine cyclic desulfurization phosphine radical sulfide sulfide;ESR sulfide;reductive tertiary voltammetry %N 4 %P 1265--1277 %T Radical ions. 48. Radical anions as intermediates in the reductive desulfurization of tertiary phosphine sulfides %V 115 %X Dimethylthiophosphinyl groups, -P(S)Me2, act as acceptor substituents toward p systems. According to cyclic voltammograms, the 1-electron acquisition often proceeds quasi-reversibly. Thus, radical anions of PhR, m-R2C6H4, p-RC6H4C6H4R-p, E-PhCH:CHR [R = Ph(S)Me2], 2,5-bis(dimethylthiophosphinyl)thiophene, and 1,4-bis(dimethylthiophosphinyl)naphthalene were detected and identified by their ESR spectra. Further redn. leads to desulfurization. [on SciFinder(R)]

@article{Kaim.1982b, abstract = {Dimethylthiophosphinyl groups, -P(S)Me2, act as acceptor substituents toward \textgreek{p} systems. According to cyclic voltammograms, the 1-electron acquisition often proceeds quasi-reversibly. Thus, radical anions of PhR, m-R2C6H4, p-RC6H4C6H4R-p, E-PhCH:CHR [R = Ph(S)Me2], 2,5-bis(dimethylthiophosphinyl)thiophene, and 1,4-bis(dimethylthiophosphinyl)naphthalene were detected and identified by their ESR spectra. Further redn. leads to desulfurization. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Haenel, Peter and Lechner-Knoblauch, Ulrike and Bock, Hans.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2cd4715223617da73e98a813cf391ec23/huebleriac}, interhash = {fab87c5d539846b35a87f3e7621b7fa9}, intrahash = {cd4715223617da73e98a813cf391ec23}, issn = {0009-2940}, journal = {Chemische Berichte}, keywords = {anion anion;phosphine anion;radical aryldimethyl aryldimethylphosphine cyclic desulfurization phosphine radical sulfide sulfide;ESR sulfide;reductive tertiary voltammetry}, number = 4, pages = {1265--1277}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Radical ions. 48. Radical anions as intermediates in the reductive desulfurization of tertiary phosphine sulfides}, volume = 115, year = 1982 }