%0 Journal Article %1 Moorlag.2006 %A Moorlag, Carolyn %A Sarkar, Biprajit %A Sanrame, Carlos N. %A Baeuerle, Peter %A Kaim, Wolfgang %A Wolf, Michael O. %D 2006 %J Inorganic Chemistry %K bipyridine bipyridyl chain complex excited ground phosphine phosphinothiophene photoexcitation photolysis;oligothienyl ruthenium state %N 18 %P 7044--7046 %R 10.1021/ic060912n %T Conjugation Length Dependent Ground and Excited State Electronic Behavior in Oligothienyl Ru Complexes %V 45 %X Photoexcitation of a bis(bipyridyl)-Ru(II) complex bearing a phosphinopentathiophene ligand results in formation of a transient species with a lifetime of 2.2 ms. The transient is attributed to the product of an intramol. charge transfer from the pentathiophene ligand. EPR and UV/vis spectroelectrochem. show that the HOMO is pentathienyl-based, while corresponding complexes with shorter conjugation length ligands have a metal-based HOMO and do not exhibit long-lived transients. on SciFinder(R)

@article{Moorlag.2006, abstract = {Photoexcitation of a bis(bipyridyl)-Ru(II) complex bearing a phosphinopentathiophene ligand results in formation of a transient species with a lifetime of 2.2 \textgreek{m}s. The transient is attributed to the product of an intramol. charge transfer from the pentathiophene ligand. EPR and UV/vis spectroelectrochem. show that the HOMO is pentathienyl-based, while corresponding complexes with shorter conjugation length ligands have a metal-based HOMO and do not exhibit long-lived transients. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Moorlag, Carolyn and Sarkar, Biprajit and Sanrame, Carlos N. and Baeuerle, Peter and Kaim, Wolfgang and Wolf, Michael O.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/253ce401230a4bf08f704c08ae49cb46d/huebleriac}, doi = {10.1021/ic060912n}, interhash = {f88bc683c9342586a4c8f6b6b0374d81}, intrahash = {53ce401230a4bf08f704c08ae49cb46d}, issn = {0020-1669}, journal = {Inorganic Chemistry}, keywords = {bipyridine bipyridyl chain complex excited ground phosphine phosphinothiophene photoexcitation photolysis;oligothienyl ruthenium state}, number = 18, pages = {7044--7046}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Conjugation Length Dependent Ground and Excited State Electronic Behavior in Oligothienyl Ru Complexes}, volume = 45, year = 2006 }