%0 Journal Article %1 Sixt.2000b %A Sixt, T. %A Fiedler, J. %A Kaim, W. %D 2000 %J Inorganic Chemistry Communications %K bimetallic complex complex;ESR dppf electrochem iron oxidn ruthenium spectroelectrochem %N 2 %P 80--82 %R 10.1016/S1387-7003(00)00009-5 %T Iron versus ruthenium oxidation in 1,1'-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes: EPR and spectroelectrochemical evidence %V 3 %X Oxidn. of [Cp*RuH(dppf)] (1), dppf = 1,1'-bis(diphenylphosphino)ferrocene, and [(Cym)RuCl(dppf)](PF6) (2), Cym = p-cymene, occurs at Ru for 1 but yields a ferrocenium species for compd. 2. The preference of Ru over Fe oxidn. is a consequence of the more donating hydride and cyclopentadienide ligands in 1 in comparison with the arene/chloride combination in 2. [on SciFinder(R)]

@article{Sixt.2000b, abstract = {Oxidn. of [Cp*RuH(dppf)] (1), dppf = 1,1'-bis(diphenylphosphino)ferrocene, and [(Cym)RuCl(dppf)](PF6) (2), Cym = p-cymene, occurs at Ru for 1 but yields a ferrocenium species for compd. 2. The preference of Ru over Fe oxidn. is a consequence of the more donating hydride and cyclopentadienide ligands in 1 in comparison with the arene/chloride combination in 2. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Sixt, T. and Fiedler, J. and Kaim, W.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2dcaa5a1286c2cef19d11bd50fa840838/huebleriac}, doi = {10.1016/S1387-7003(00)00009-5}, interhash = {e61f6e622bb0613105d7efc7f54876dd}, intrahash = {dcaa5a1286c2cef19d11bd50fa840838}, issn = {1387-7003}, journal = {Inorganic Chemistry Communications}, keywords = {bimetallic complex complex;ESR dppf electrochem iron oxidn ruthenium spectroelectrochem}, number = 2, pages = {80--82}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Iron versus ruthenium oxidation in 1,1'-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes: EPR and spectroelectrochemical evidence}, volume = 3, year = 2000 }