%0 Journal Article %1 AK01 %A Schooss, Detlef %A Gilb, Stefan %A Kaller, Julian %A Kappes, Manfred M. %A Furche, Filipp %A Köhn, Andreas %A May, Klaus %A Ahlrichs, Reinhart %D 2000 %J J. Chem. Phys. %K chemie imported koehn köhn from:alexanderdenzel theoretische stuttgart theochem %N 13 %P 5361–5371 %R 10.1063/1.1290028 %T Photodissociation spectroscopy of Ag₄⁺(N₂)ₘ, m = 0-4 %U http://dx.doi.org/10.1063/1.1290028 %V 113 %X We have determined photodissociation spectra of Ag-4(+)(N- 2)(m=0-4) in the photon energy range from 2.1 to 3.75 eV. The cluster complexes were generated by laser vaporization and their absolute photodissociation cross sections were measured in depletion using a modified reflectron time-of-flight mass spectrometer. The band spectra show significant nonmonotonic variations with increasing N-2 coverage. The experimental data are contrasted with quantum chemical calculations of ground and electronically excited states using density functional as well as post-Hartree-Fock methods. Experiment and theory are in qualitative agreement allowing tentative assignment of the depletion spectra and insight into the relevant bonding interactions. (C) 2000 American Institute of Physics. ［S0021- 9606(00)01137-5］. %@ 0021-9606

@article{AK01, abstract = {We have determined photodissociation spectra of Ag-4(+)(N- 2)(m=0-4) in the photon energy range from 2.1 to 3.75 eV. The cluster complexes were generated by laser vaporization and their absolute photodissociation cross sections were measured in depletion using a modified reflectron time-of-flight mass spectrometer. The band spectra show significant nonmonotonic variations with increasing N-2 coverage. The experimental data are contrasted with quantum chemical calculations of ground and electronically excited states using density functional as well as post-Hartree-Fock methods. Experiment and theory are in qualitative agreement allowing tentative assignment of the depletion spectra and insight into the relevant bonding interactions. (C) 2000 American Institute of Physics. ［S0021- 9606(00)01137-5］.}, added-at = {2019-02-06T13:16:27.000+0100}, author = {Schooss, Detlef and Gilb, Stefan and Kaller, Julian and Kappes, Manfred M. and Furche, Filipp and K{\"{o}}hn, Andreas and May, Klaus and Ahlrichs, Reinhart}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2170e6093370f3cb7616abcdf8f7fc332/theochem}, doi = {10.1063/1.1290028}, interhash = {da7155ead6a0c3a69e261585ad9812e5}, intrahash = {170e6093370f3cb7616abcdf8f7fc332}, isbn = {0021-9606}, issn = {00219606}, journal = {J. Chem. Phys.}, keywords = {chemie imported koehn köhn from:alexanderdenzel theoretische stuttgart theochem}, number = 13, pages = {5361–5371}, timestamp = {2019-02-06T12:16:27.000+0100}, title = {{Photodissociation spectroscopy of Ag₄⁺(N₂)ₘ, m = 0-4}}, url = {http://dx.doi.org/10.1063/1.1290028}, volume = 113, year = 2000 }