%0 Journal Article %1 publ9383191 %A Senekowitsch, J %A Carter, S %A Werner, H J %A Rosmus, P %D 1987 %J Chem. Phys. Lett. %K chemie imported werner from:alexanderdenzel theoretische stuttgart theochem %N 4 %P 375–380 %R 10.1016/0009-2614(87)80750-9 %T Vibrational radiative lifetimes in H₂Se and HCS- %U http://dx.doi.org/10.1016/0009-2614(87)80750-9 %V 140 %X Vibrational dipole matrix elements and radiative transition probabilities for H₂Se and HCS-have been evaluated from theoretical three-dimensional electric dipole moment and potential energy functions. The radiative lifetimes of the (v=1,J=0) levels of HCS-have been calculated to be 3.5 ms (CH stretch), 172 ms (HCS bend) and 785 ms (CS stretch), and in H₂Se to be 122 ms (symmetric stretch), 1045 ms (bend) and 101 ms (asymmetric stretch). The lifetimes of higher vibrational states with no extensive mode-mixing decrease with increasing vibrational quantum number and vary in a mode-specific way. ©1987.

@article{publ9383191, abstract = {Vibrational dipole matrix elements and radiative transition probabilities for H₂Se and HCS-have been evaluated from theoretical three-dimensional electric dipole moment and potential energy functions. The radiative lifetimes of the (v=1,J=0) levels of HCS-have been calculated to be 3.5 ms (CH stretch), 172 ms (HCS bend) and 785 ms (CS stretch), and in H₂Se to be 122 ms (symmetric stretch), 1045 ms (bend) and 101 ms (asymmetric stretch). The lifetimes of higher vibrational states with no extensive mode-mixing decrease with increasing vibrational quantum number and vary in a mode-specific way. {\textcopyright}1987.}, added-at = {2019-03-01T15:49:43.000+0100}, author = {Senekowitsch, J and Carter, S and Werner, H J and Rosmus, P}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d30e0b022609c4f8cb298496f9839086/theochem}, doi = {10.1016/0009-2614(87)80750-9}, interhash = {d43bf7c3e1e9e2bbc62ea5e328ea7285}, intrahash = {d30e0b022609c4f8cb298496f9839086}, issn = {00092614}, journal = {Chem. Phys. Lett.}, keywords = {chemie imported werner from:alexanderdenzel theoretische stuttgart theochem}, number = 4, pages = {375–380}, timestamp = {2019-03-01T14:49:43.000+0100}, title = {{Vibrational radiative lifetimes in H₂Se and HCS-}}, url = {http://dx.doi.org/10.1016/0009-2614(87)80750-9}, volume = 140, year = 1987 }