Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands
, and .
Zeitschrift fuer Anorganische und Allgemeine Chemie (1989)

Re(CO)3ClL (L = pyrazine-2-dimethylcarboxamide, 1-ethylpyrazinium-3-dimethylcarboxamide, 1,3-dimethyllumazine, 2,5-diacetylpyrazine, lumiflavine and riboflavin were prepd. and studied by cyclic voltammetry and spectroscopy (IR, electronic, ESR). s-Polarization and p-back-bonding by the organometallic fragment cause stabilization of the reduced (radical) form and of the first metal-to-ligand charge transfer excited state. on SciFinder(R)
  • @b_schwederski
This publication has not been reviewed yet.

rating distribution
average user rating0.0 out of 5.0 based on 0 reviews
    Please log in to take part in the discussion (add own reviews or comments).