Article,

Bridging the fields of organometallic and classical coordination chemistry: Localized and delocalized bonding in polynuclear complexes of (C5R5)(CO)2Mn

, and .
Comments on Inorganic Chemistry, 7 (5): 269--285 (1988)
DOI: 10.1080/02603598808072312

Abstract

A review contg. 37 refs. The capability of the title fragment to undergo efficient p back bonding, to exist in two kinetically stable neighboring oxidn. states, and to exhibit a relatively small ligand field splitting allow the formation of unusual coordination compds. Several mono- and polynuclear examples with an odd or even electron count and different degrees and direction of electron delocalization between ligand and metal fragment(s) are discussed. on SciFinder(R)

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