%0 Journal Article %1 Schomburg1978 %A Schomburg, Heinrich %A Staerk, Hubert %A Weller, Albert %A Werner, Hans Joachim %D 1978 %J Chem. Phys. Lett. %K chemie imported werner from:alexanderdenzel theoretische stuttgart theochem %N 3 %P 399–403 %R 10.1016/0009-2614(78)89001-0 %T Temperature dependence of the geminate recombination of radical ion pairs %U http://dx.doi.org/10.1016/0009-2614(78)89001-0 %V 56 %X The photoinduced formation of radical ion pairs (in fluorescence quenching) and their geminate recombination to give singlet (ground state) and triplet product states is studied at different temperatures between 233 and 296 K with the system pyrene/N,N-dimethylaniline (DMA) in methanol. The geminate singlet recombination yield is found to be strongly increasing with decreasing temperature, whereas the triplet yield is virtually independent of temperature. These results are in agreement with previous theoretical predictions. © 1978.

@article{Schomburg1978, abstract = {The photoinduced formation of radical ion pairs (in fluorescence quenching) and their geminate recombination to give singlet (ground state) and triplet product states is studied at different temperatures between 233 and 296 K with the system pyrene/N,N-dimethylaniline (DMA) in methanol. The geminate singlet recombination yield is found to be strongly increasing with decreasing temperature, whereas the triplet yield is virtually independent of temperature. These results are in agreement with previous theoretical predictions. {\textcopyright} 1978.}, added-at = {2019-03-01T15:49:44.000+0100}, author = {Schomburg, Heinrich and Staerk, Hubert and Weller, Albert and Werner, Hans Joachim}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27420e98bc163710951477a238d758371/theochem}, doi = {10.1016/0009-2614(78)89001-0}, interhash = {b94890c1a9f616041395d83ccb739864}, intrahash = {7420e98bc163710951477a238d758371}, issn = {00092614}, journal = {Chem. Phys. Lett.}, keywords = {chemie imported werner from:alexanderdenzel theoretische stuttgart theochem}, month = jun, number = 3, pages = {399–403}, timestamp = {2019-03-01T14:49:44.000+0100}, title = {{Temperature dependence of the geminate recombination of radical ion pairs}}, url = {http://dx.doi.org/10.1016/0009-2614(78)89001-0}, volume = 56, year = 1978 }