%0 Journal Article %1 Vogler.1989 %A Vogler, Conny %A Hausen, Hans Dieter %A Kaim, Wolfgang %A Kohlmann, Stephan %A Kramer, Horst E. A. %A Rieker, Jochen. %D 1989 %J Angewandte Chemie %K arsine bipyrimidine copper dinuclear dinuclear;crystal dinuclear;luminescence dinuclear;structure phenylphosphine phosphine structure %N 12 %P 1734--1735 %T Copper(I)-induced formation of an organic sandwich structure. Structural hypothesis for luminescence of binuclear copper bipyrimidine complexes %V 101 %X (m-Bpym)Cu(PR3)22(BF4)2 (I; bpym = bipyrimidine; R = Ph, C6D5, o-, m- and p-MeC6H4, C6F5, p-ClC6H4, p-Me2NC6H4), (m-bpym)Cu(PR1R22)22(BF4)2 (II; R1 = H, Me, R2 = Ph; R1 = p-MeC6H4, R2 = Me) and (m-bpym)Cu(Ph2P(CH2)nPPh2)2(BF4)2 (III; n = 1-5) were prepd. from Cu, Cu(BF4)2, bpym and phosphine in MeOH under reflux. I.MeOH.H2O (R = Ph) is triclinic, space group P1̅, a 1192.4(2), b 1253.7(3), c 1457.3(3) pm, a 65.57(2), b 71.76(2), g 74.88(2)°, Z = 1, dc = 1.34 g cm-3, R = 0.039, Rw = 0.035. I.MeOH.H2O (R = Ph) has intense luminescence in the solid state which in soln. is not intense before or after anion exchange with PF6- or ClO4-; I (R $\not=$ Ph, C6D5, or m-MeC6H4) and II do not luminesce. I (R = C6D5, m-MeC6H4), the Ph3As analog of I and III (n = 5) have similar luminescent properties in the solid state. For I.MeOH.H2O (R = Ph) the intramol. Cu-Cu distance is 562.2 pm and the intermol. Cu-Cu distance is \textgreater953.3 pm. The space across the bridging bpym ligand is so large that the Ph ring of Ph3P is involved in p-exchange interaction with the p-acceptor heterocycle bpym. This allows luminescence to occur. on SciFinder(R)

@article{Vogler.1989, abstract = {[(\textgreek{m}-Bpym){Cu(PR3)2}2](BF4)2 (I; bpym = bipyrimidine; R = Ph, C6D5, o-, m- and p-MeC6H4, C6F5, p-ClC6H4, p-Me2NC6H4), [(\textgreek{m}-bpym){Cu(PR1R22)2}2](BF4)2 (II; R1 = H, Me, R2 = Ph; R1 = p-MeC6H4, R2 = Me) and [(\textgreek{m}-bpym){Cu(Ph2P(CH2)nPPh2)}2](BF4)2 (III; n = 1-5) were prepd. from Cu, Cu(BF4)2, bpym and phosphine in MeOH under reflux. I.MeOH.H2O (R = Ph) is triclinic, space group P1̅, a 1192.4(2), b 1253.7(3), c 1457.3(3) pm, \textgreek{a} 65.57(2), \textgreek{b} 71.76(2), \textgreek{g} 74.88(2)°, Z = 1, dc = 1.34 g cm-3, R = 0.039, Rw = 0.035. I.MeOH.H2O (R = Ph) has intense luminescence in the solid state which in soln. is not intense before or after anion exchange with PF6- or ClO4-; I (R $\not=$ Ph, C6D5, or m-MeC6H4) and II do not luminesce. I (R = C6D5, m-MeC6H4), the Ph3As analog of I and III (n = 5) have similar luminescent properties in the solid state. For I.MeOH.H2O (R = Ph) the intramol. Cu-Cu distance is 562.2 pm and the intermol. Cu-Cu distance is {\textgreater}953.3 pm. The space across the bridging bpym ligand is so large that the Ph ring of Ph3P is involved in \textgreek{p}-exchange interaction with the \textgreek{p}-acceptor heterocycle bpym. This allows luminescence to occur. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Vogler, Conny and Hausen, Hans Dieter and Kaim, Wolfgang and Kohlmann, Stephan and Kramer, Horst E. A. and Rieker, Jochen.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/296857a0804010d6938691aec1c0a8bb8/huebleriac}, interhash = {9665fee9ce8b9f219745ba19d43b753c}, intrahash = {96857a0804010d6938691aec1c0a8bb8}, issn = {0044-8249}, journal = {Angewandte Chemie}, keywords = {arsine bipyrimidine copper dinuclear dinuclear;crystal dinuclear;luminescence dinuclear;structure phenylphosphine phosphine structure}, number = 12, pages = {1734--1735}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Copper(I)-induced formation of an organic sandwich structure. Structural hypothesis for luminescence of binuclear copper bipyrimidine complexes}, volume = 101, year = 1989 }