%0 Journal Article %1 Ketterle.1998 %A Ketterle, Michael %A Kaim, Wolfgang %A Fiedler, Jan. %D 1998 %J Chemical Communications (Cambridge, United Kingdom) %K bridged bridged;iron bridged;valence comproportionation const cyano delocalization dinuclear iron prepn;mixed pyrimidyltetrazine valent %N 16 %P 1701--1702 %R 10.1039/a804279i %T Valence delocalization in a strongly coupled (Kc = 1014) molecule-bridged cyanodiiron(III,II) species %X A hybrid between the Prussian Blue and Creutz-Taube mixed valent species is presented as the newly prepd. bmtz-bridged bis[tetracyanoiron(+2.5)] complex (13-) [bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine] which exhibits a very large comproportionation const. of 1014 and a delocalized structure, according to UV-visible-NIR-IR spectroelectrochem. in MeCN soln. [on SciFinder(R)]

@article{Ketterle.1998, abstract = {A hybrid between the Prussian Blue and Creutz-Taube mixed valent species is presented as the newly prepd. bmtz-bridged bis[tetracyanoiron(+2.5)] complex (13-) [bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine] which exhibits a very large comproportionation const. of 1014 and a delocalized structure, according to UV-visible-NIR-IR spectroelectrochem. in MeCN soln. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Ketterle, Michael and Kaim, Wolfgang and Fiedler, Jan.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2e35895f55884670990e74fa3a9b462f5/huebleriac}, doi = {10.1039/a804279i}, interhash = {80a2fbbd02da89e13047bfc3079601c1}, intrahash = {e35895f55884670990e74fa3a9b462f5}, issn = {1359-7345}, journal = {Chemical Communications (Cambridge, United Kingdom)}, keywords = {bridged bridged;iron bridged;valence comproportionation const cyano delocalization dinuclear iron prepn;mixed pyrimidyltetrazine valent}, number = 16, pages = {1701--1702}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Valence delocalization in a strongly coupled (Kc = 1014) molecule-bridged cyanodiiron(III,II) species}, year = 1998 }