%0 Journal Article %1 Wang.2003 %A Wang, Jianhui %A Li, Shoujian %A Zheng, Chong %A Hosmane, Narayan S. %A Maguire, John A. %A Roesky, Herbert W. %A Cummins, Christopher C. %A Kaim, Wolfgang. %D 2003 %J Organometallics %K THF cluster complex;oxide crystal dicarbahexaborate encapsulating holmacarborane holmium ion mol prepn reaction sodium structure trichloride %N 22 %P 4390--4392 %R 10.1021/om034019x %T An Oxide Ion Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the \dqCarbons Apart\dq C2B4-Carborane Ligands %V 22 %X The reaction of closo-exo-5,6-Na(THF)2-1-Na(THF)2-2,4-(SiMe3)2-2,4-C2B4H4 with HoCl3 and H2O in a molar ratio of 5:4:1 produces the new holmacarborane cluster η5-1-Ho(THF)-2,3-(SiMe3)2-2,3-C2B4H44(μ-Cl)2(μ4-O) as a pale yellow cryst. solid in 86\% yield. The crystal structure shows that the core of the cluster consists of four Ho atoms that tetrahedrally surround an O atom. on SciFinder(R)

@article{Wang.2003, abstract = {The reaction of closo-exo-5,6-Na(THF)2-1-Na(THF)2-2,4-(SiMe3)2-2,4-C2B4H4 with HoCl3 and H2O in a molar ratio of 5:4:1 produces the new holmacarborane cluster {[η5-1-Ho(THF)-2,3-(SiMe3)2-2,3-C2B4H4]4(μ-Cl)2(μ4-O)} as a pale yellow cryst. solid in 86{\%} yield. The crystal structure shows that the core of the cluster consists of four Ho atoms that tetrahedrally surround an O atom. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Wang, Jianhui and Li, Shoujian and Zheng, Chong and Hosmane, Narayan S. and Maguire, John A. and Roesky, Herbert W. and Cummins, Christopher C. and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27033ba5f9b0231c17a7c559bc9deee94/huebleriac}, doi = {10.1021/om034019x}, interhash = {70e2803b595e2fd4620ad3182d93cf90}, intrahash = {7033ba5f9b0231c17a7c559bc9deee94}, issn = {0276-7333}, journal = {Organometallics}, keywords = {THF cluster complex;oxide crystal dicarbahexaborate encapsulating holmacarborane holmium ion mol prepn reaction sodium structure trichloride}, number = 22, pages = {4390--4392}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {An Oxide Ion Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the {\dq}Carbons Apart{\dq} C2B4-Carborane Ligands}, volume = 22, year = 2003 }