%0 Journal Article %1 publ9368211 %A Hochlaf, M. %A Chambaud, G. %A Rosmus, P. %A Andersen, T. %A Werner, H. J. %D 1999 %J J. Chem. Phys. %K chemie imported werner from:alexanderdenzel theoretische stuttgart theochem %N 24 %P 11835–11840 %R 10.1063/1.479125 %T Quartet and sextet states of CS- %U http://dx.doi.org/10.1063/1.479125 %V 110 %X The potential energy and spin–orbit functions have been calculated for several electronic states of CS and CS−. Comparison with experimental data for CS shows very good agreement, making reliable predictions possible for the CS− molecule such as the existence of long-lived metastable states. The a 4Σ−, b 4Π, and a 6Π states were found to lie energetically below the triplet or quintet states of the CS molecule. The calculated spin–orbit integrals between the electronic states suggest that the depletion of the J = 5/2 or 7/2 components in the Π states will mainly occur via weak interactions with the electron continuum wave. © 1999 American Institute of Physics.

@article{publ9368211, abstract = {The potential energy and spin–orbit functions have been calculated for several electronic states of CS and CS−. Comparison with experimental data for CS shows very good agreement, making reliable predictions possible for the CS− molecule such as the existence of long-lived metastable states. The a 4Σ−, b 4Π, and a 6Π states were found to lie energetically below the triplet or quintet states of the CS molecule. The calculated spin–orbit integrals between the electronic states suggest that the depletion of the J = 5/2 or 7/2 components in the Π states will mainly occur via weak interactions with the electron continuum wave. {\textcopyright} 1999 American Institute of Physics.}, added-at = {2019-03-01T15:49:42.000+0100}, author = {Hochlaf, M. and Chambaud, G. and Rosmus, P. and Andersen, T. and Werner, H. J.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2fe902210ca9d34909ca0add3c7f227ec/theochem}, doi = {10.1063/1.479125}, interhash = {5c753de1488f9fdc3057a0ce921b40c9}, intrahash = {fe902210ca9d34909ca0add3c7f227ec}, issn = {00219606}, journal = {J. Chem. Phys.}, keywords = {chemie imported werner from:alexanderdenzel theoretische stuttgart theochem}, number = 24, pages = {11835–11840}, timestamp = {2019-03-01T14:49:42.000+0100}, title = {{Quartet and sextet states of CS-}}, url = {http://dx.doi.org/10.1063/1.479125}, volume = 110, year = 1999 }