%0 Journal Article %1 Kinauer.2018 %A Kinauer, Markus %A Diefenbach, Martin %A Bamberger, Heiko %A Demeshko, Serhiy %A Reijerse, Edward J. %A Volkmann, Christian %A Würtele, Christian %A van Slageren, Joris %A de Bruin, Bas %A Holthausen, Max C. %A Schneider, Sven %D 2018 %J Chemical science %K agvsl imported %N 18 %P 4325--4332 %R 10.1039/c8sc01113c %T An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state %V 9 %X The iridium(iii/iv/v) imido redox series Ir(NtBu)N(CHCHPtBu2)20/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(iv) imide exhibits an electronic doublet ground state with considerable 'imidyl' character as a result of covalent Ir-NtBu bonding. Reduction gives the neutral imide Ir(NtBu)N(CHCHPtBu2)2 as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO2) and nucleophiles (PMe3), respectively, is reported.

@article{Kinauer.2018, abstract = {The iridium(iii/iv/v) imido redox series [Ir(NtBu){N(CHCHPtBu2)2}]0/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(iv) imide exhibits an electronic doublet ground state with considerable 'imidyl' character as a result of covalent Ir-NtBu bonding. Reduction gives the neutral imide [Ir(NtBu){N(CHCHPtBu2)2}] as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO2) and nucleophiles (PMe3), respectively, is reported.}, added-at = {2018-10-26T17:40:08.000+0200}, author = {Kinauer, Markus and Diefenbach, Martin and Bamberger, Heiko and Demeshko, Serhiy and Reijerse, Edward J. and Volkmann, Christian and Würtele, Christian and {van Slageren}, Joris and de Bruin, Bas and Holthausen, Max C. and Schneider, Sven}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2ed03d3afc7334ad8b2079e2510ec471e/mariowinkler}, doi = {10.1039/c8sc01113c}, interhash = {5bd76c397ec07555304c340e92b0357b}, intrahash = {ed03d3afc7334ad8b2079e2510ec471e}, issn = {2041-6520}, journal = {Chemical science}, keywords = {agvsl imported}, number = 18, pages = {4325--4332}, timestamp = {2018-10-26T15:50:00.000+0200}, title = {An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state}, volume = 9, year = 2018 }