%0 Journal Article %1 Matheis.1991b %A Matheis, Walter %A Kaim, Wolfgang. %D 1991 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K bipyridine bipyrimidine carbonyl copper dinuclear;molybdenum dinuclear;redn dinuclear;rhenium electrochem heterodinuclear heterodinuclear;electrochem heterodinuclear;oxidn heterodinuclear;ruthenium heterodinuclear;solvatochromism homodinuclear metal phosphine redox transition %P 147--159 %R 10.1002/zaac.19915930114 %T Homo- and heterodinuclear complexes of D2h-symmetric bis(chelate) ligand 2,2'-bipyrimidine with electron-rich metal fragments Mo(CO)4, Re(CO)3Cl, Cu(PPh3)2+, and Ru(bpy)22+ %V 593 %X (LnM)(m-bpym)(MLn) (bpym = 2,2'-bipyrimidine, MLn, (MLn)' = Mo(CO)4, Re(CO)3Cl, Cu(PPh3)2+, Ru(bpy)22+) were synthesized and studied by cyclic voltammetry, absorption spectroscopy, and ESR of singly reduced forms. The individual capabilities of the low-valent metal fragments to undergo oxidn. and to shift the redn. potential of the bpym p acceptor ligand on coordination combine to result in variable electrochem. potential differences. After consideration of different Franck-Condon factors, absorption intensities, addnl. low-lying unoccupied orbitals of the bridging acceptor ligand, and solvatochromic effects, the considerably varying metal-to-ligand charge transfer transitions in the visible were assigned. on SciFinder(R)

@article{Matheis.1991b, abstract = {(LnM)(\textgreek{m}-bpym)(MLn) (bpym = 2,2'-bipyrimidine, MLn, (MLn)' = Mo(CO)4, Re(CO)3Cl, [Cu(PPh3)2]+, [Ru(bpy)2]2+) were synthesized and studied by cyclic voltammetry, absorption spectroscopy, and ESR of singly reduced forms. The individual capabilities of the low-valent metal fragments to undergo oxidn. and to shift the redn. potential of the bpym \textgreek{p} acceptor ligand on coordination combine to result in variable electrochem. potential differences. After consideration of different Franck-Condon factors, absorption intensities, addnl. low-lying unoccupied orbitals of the bridging acceptor ligand, and solvatochromic effects, the considerably varying metal-to-ligand charge transfer transitions in the visible were assigned. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Matheis, Walter and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2aaeaabd6e195f1ae328317423747ac1e/huebleriac}, doi = {10.1002/zaac.19915930114}, interhash = {3f9a1e882ea73212107b6a4525ad5f35}, intrahash = {aaeaabd6e195f1ae328317423747ac1e}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {bipyridine bipyrimidine carbonyl copper dinuclear;molybdenum dinuclear;redn dinuclear;rhenium electrochem heterodinuclear heterodinuclear;electrochem heterodinuclear;oxidn heterodinuclear;ruthenium heterodinuclear;solvatochromism homodinuclear metal phosphine redox transition}, pages = {147--159}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Homo- and heterodinuclear complexes of D2h-symmetric bis(chelate) ligand 2,2'-bipyrimidine with electron-rich metal fragments Mo(CO)4, Re(CO)3Cl, [Cu(PPh3)2]+, and [Ru(bpy)2]2+}, volume = 593, year = 1991 }