%0 Journal Article %1 Sixt.2000 %A Sixt, Torsten %A Kaim, Wolfgang %A Preetz, Wilhelm. %D 2000 %J Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences %K chloroosmate chloroosmate;pentamethylcyclopentadiene complexation crystal osmium pentamethylcyclopentadienyl prepn;mol structure trichloride %N 3/4 %P 235--237 %T Characterization of the inorganic/organometallic osmium(IV) compound Cp*2OsIVCl2OsIVCl6 as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air %V 55 %X Reaction of OsCl3 with pentamethylcyclopentadiene in EtOH in air yields the ionic Os(IV) compd. Cp*2OsCl2OsCl6 which was identified structurally and by vibrational spectroscopy. Under comparable conditions the RuCl3 homolog yields the Ru(III) compd. Cp*RuCl22, illustrating the more facile oxidn. of the 5d element to the tetravalent state. on SciFinder(R)

@article{Sixt.2000, abstract = {Reaction of OsCl3 with pentamethylcyclopentadiene in EtOH in air yields the ionic Os(IV) compd. [Cp*2OsCl]2[OsCl6] which was identified structurally and by vibrational spectroscopy. Under comparable conditions the RuCl3 homolog yields the Ru(III) compd. [Cp*RuCl2]2, illustrating the more facile oxidn. of the 5d element to the tetravalent state. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Sixt, Torsten and Kaim, Wolfgang and Preetz, Wilhelm.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2bb445aa7d0f0686c7d004be1091cda66/huebleriac}, interhash = {3df3ad72155d7f428293382695810b41}, intrahash = {bb445aa7d0f0686c7d004be1091cda66}, issn = {0932-0776}, journal = {Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences}, keywords = {chloroosmate chloroosmate;pentamethylcyclopentadiene complexation crystal osmium pentamethylcyclopentadienyl prepn;mol structure trichloride}, number = {3/4}, pages = {235--237}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Characterization of the inorganic/organometallic osmium(IV) compound [Cp*2OsIVCl]2[OsIVCl6] as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air}, volume = 55, year = 2000 }