%0 Journal Article %1 Cotton.1979b %A Cotton, F. Albert %A Ilsley, William H. %A Kaim, Wolfgang. %D 1979 %J Inorganica Chimica Acta %K acetato binuclear complex;structure molybdenum phenyliminopentanonato %N 2 %P 267--272 %R 10.1016/S0020-1693(00)95556-7 %T Chelate rings in a quadruply bonded dimetal compound: Preparation and structure of diacetatodi(4-phenylimino-2-pentanonato)dimolybdenum %V 37 %X Lithium (4-phenylimino)-2-pentanonate reacts with Mo2(O2CMe)4 to replace 2 acetate ligands and afford red, cryst. Mo2(O2CMe)2[PhNCMeCHCMe(O)]2. The crystal and mol. structures were detd. by x-ray crystallog. The crystals belong to space group P1̅ with a 11.723(3), b 10.402(2), c 12.624(2) \AA; a 112.88(1)°, b 95.04(1)°, g 107.01(1)°, and Z = 2. The structure has cisoid arrangement of the bridging acetate ligands and 1 chelate ring on each metal atom. The unsym. chelate ligands are so arranged that the virtual symmetry is C2. The Mo-Mo distance is 2.131(1) \AA. [on SciFinder(R)]

@article{Cotton.1979b, abstract = {Lithium (4-phenylimino)-2-pentanonate reacts with Mo2(O2CMe)4 to replace 2 acetate ligands and afford red, cryst. Mo2(O2CMe)2[PhNCMeCHCMe(O)]2. The crystal and mol. structures were detd. by x-ray crystallog. The crystals belong to space group P1̅ with a 11.723(3), b 10.402(2), c 12.624(2) {\AA}; \textgreek{a} 112.88(1)°, \textgreek{b} 95.04(1)°, \textgreek{g} 107.01(1)°, and Z = 2. The structure has cisoid arrangement of the bridging acetate ligands and 1 chelate ring on each metal atom. The unsym. chelate ligands are so arranged that the virtual symmetry is C2. The Mo-Mo distance is 2.131(1) {\AA}. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Cotton, F. Albert and Ilsley, William H. and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2328692a47d62584c32a9624937118f92/huebleriac}, doi = {10.1016/S0020-1693(00)95556-7}, interhash = {33c2394bb66936156641efb321bf9db6}, intrahash = {328692a47d62584c32a9624937118f92}, issn = {0020-1693}, journal = {Inorganica Chimica Acta}, keywords = {acetato binuclear complex;structure molybdenum phenyliminopentanonato}, number = 2, pages = {267--272}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Chelate rings in a quadruply bonded dimetal compound: Preparation and structure of diacetatodi(4-phenylimino-2-pentanonato)dimolybdenum}, volume = 37, year = 1979 }