%0 Journal Article %1 Reinhardt.1993 %A Reinhardt, Ralf %A Kaim, Wolfgang. %D 1993 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K UV complex complex;diazabutadiene cyclic diimine electrochem;rhodium pentamethylcyclopentadienyl pentamethylcyclopentadienylrhodium prepn voltammetry %N 12 %P 1998--2005 %T Complexes of a-diimines with pentamethylcyclopentadienylrhodium in different oxidation states %V 619 %X Cationic complexes Cp*RhCl(a-diimine)+ of trivalent rhodium and heterocyclic a-diimines or 1,4-disubstituted 1,4-diazabutadienes were isolated as hexafluorophosphates and subjected to electrochem. studies. Chem. or electrochem. two electron redn. yields intensely colored and highly reactive neutral complexes Cp*Rh(a-diimine) which are very easily oxidized and which can be reduced further at neg. potentials. The electronic structure of these compds. was studied using 1H-NMR and UV/Vis spectroscopy. Comparisons of charge transfer (CT) transition energies with redox potentials suggest very variable geometrical changes between ground and CT excited states. on SciFinder(R)

@article{Reinhardt.1993, abstract = {Cationic complexes [Cp*RhCl(\textgreek{a}-diimine)]+ of trivalent rhodium and heterocyclic \textgreek{a}-diimines or 1,4-disubstituted 1,4-diazabutadienes were isolated as hexafluorophosphates and subjected to electrochem. studies. Chem. or electrochem. two electron redn. yields intensely colored and highly reactive neutral complexes Cp*Rh(\textgreek{a}-diimine) which are very easily oxidized and which can be reduced further at neg. potentials. The electronic structure of these compds. was studied using 1H-NMR and UV/Vis spectroscopy. Comparisons of charge transfer (CT) transition energies with redox potentials suggest very variable geometrical changes between ground and CT excited states. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Reinhardt, Ralf and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27fd87499daf447df52eae24ed953ffa9/huebleriac}, interhash = {33abf273b6b5b9501e8e1bb5d49ab5f8}, intrahash = {7fd87499daf447df52eae24ed953ffa9}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {UV complex complex;diazabutadiene cyclic diimine electrochem;rhodium pentamethylcyclopentadienyl pentamethylcyclopentadienylrhodium prepn voltammetry}, number = 12, pages = {1998--2005}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Complexes of \textgreek{a}-diimines with pentamethylcyclopentadienylrhodium in different oxidation states}, volume = 619, year = 1993 }