Cothermolysis of white phosphorus (P4) with (h5-C5Me5)2(CO)nW2 (C5Me5 = pentamethylcyclopentadienyl; n = 4, 6) as well as (h5-C5Me4R)V(CO)4 affords the triple-decker sandwich complexes (η5-C5Me5)W2(m,h6-cycloP6) (I) and (η5-C5Me4R)V2(m,h6-cycloP6) (II; R = Me, Et). I and II (R = Et) were characterized by x-ray structure analyses. Electrochem., ESR, and electronic spectroscopy measurements of I, II (R = Me), (η5-C5Me5)Cr2-P5, and (η5-C5Me5)Mo2-P6 were reported. An empirical valence-electron rule for triple-decker complexes is derived. on SciFinder(R)
%0 Journal Article
%1 Scherer.1988
%A Scherer, Otto J.
%A Schwalb, Joachim
%A Swarowsky, Herbert
%A Wolmershaeuser, Gotthelf
%A Kaim, Wolfgang
%A Gross, Renate.
%D 1988
%J Chemische Berichte
%K complex;triple complex;tungsten crystal cyclophosphorus decker hexaphosphacyclohexane metal sandwich sandwich;mol structure structure;vanadium tungsten vanadium;redox
%N 3
%P 443--449
%T Triple-decker sandwich complexes with cyclo-P6 as middle deck
%V 121
%X Cothermolysis of white phosphorus (P4) with (h5-C5Me5)2(CO)nW2 (C5Me5 = pentamethylcyclopentadienyl; n = 4, 6) as well as (h5-C5Me4R)V(CO)4 affords the triple-decker sandwich complexes (η5-C5Me5)W2(m,h6-cycloP6) (I) and (η5-C5Me4R)V2(m,h6-cycloP6) (II; R = Me, Et). I and II (R = Et) were characterized by x-ray structure analyses. Electrochem., ESR, and electronic spectroscopy measurements of I, II (R = Me), (η5-C5Me5)Cr2-P5, and (η5-C5Me5)Mo2-P6 were reported. An empirical valence-electron rule for triple-decker complexes is derived. on SciFinder(R)
@article{Scherer.1988,
abstract = {Cothermolysis of white phosphorus (P4) with [(\textgreek{h}5-C5Me5)2(CO)nW2] (C5Me5 = pentamethylcyclopentadienyl; n = 4, 6) as well as [(\textgreek{h}5-C5Me4R)V(CO)4] affords the triple-decker sandwich complexes [{(η5-C5Me5)W}2(\textgreek{m},\textgreek{h}6-cycloP6)] (I) and [{(η5-C5Me4R)V}2(\textgreek{m},\textgreek{h}6-cycloP6)] (II; R = Me, Et). I and II (R = Et) were characterized by x-ray structure analyses. Electrochem., ESR, and electronic spectroscopy measurements of I, II (R = Me), [{(η5-C5Me5)Cr}2-P5], and [{(η5-C5Me5)Mo}2-P6] were reported. An empirical valence-electron rule for triple-decker complexes is derived. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Scherer, Otto J. and Schwalb, Joachim and Swarowsky, Herbert and Wolmershaeuser, Gotthelf and Kaim, Wolfgang and Gross, Renate.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2f120813f4d6ce622b9843b62364b122e/b_schwederski},
interhash = {912db1440e6cde24b5391db9bd05cdde},
intrahash = {f120813f4d6ce622b9843b62364b122e},
issn = {0009-2940},
journal = {Chemische Berichte},
keywords = {complex;triple complex;tungsten crystal cyclophosphorus decker hexaphosphacyclohexane metal sandwich sandwich;mol structure structure;vanadium tungsten vanadium;redox},
number = 3,
pages = {443--449},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Triple-decker sandwich complexes with cyclo-P6 as middle deck},
volume = 121,
year = 1988
}
