%0 Journal Article %1 Das.2009 %A Das, Atanu Kumar %A Sarkar, Biprajit %A Duboc, Carole %A Strobel, Sabine %A Fiedler, Jan %A Zalis, Stanislav %A Lahiri, Goutam Kumar %A Kaim, Wolfgang %D 2009 %J Angewandte Chemie (International ed. in English) %K imported %N 23 %P 4242--4245 %T An odd-electron complex Ru(k)(NO(m))(Q(n))(terpy)2+ with two prototypical non-innocent ligands %V 48 %X Six combinations of oxidation states are conceivable for the paramagnetic title complex. Single-crystal X-ray diffraction, spectroscopic analysis (IR, EPR at conventional and high frequency), and DFT calculations establish that it is the iminosemiquinone radical structure that is formed: Ru(k)(NO(m))(Q(n))(terpy)(2+) (k = 2+, m = 1+, n = 1-).on SciFinder (R)

@article{Das.2009, abstract = {Six combinations of oxidation states are conceivable for the paramagnetic title complex. Single-crystal X-ray diffraction, spectroscopic analysis (IR, EPR at conventional and high frequency), and DFT calculations establish that it is the iminosemiquinone radical structure that is formed: [Ru(k)(NO(m))(Q(n))(terpy)](2+) (k = 2+, m = 1+, n = 1-).[on SciFinder (R)]}, added-at = {2019-07-15T13:41:23.000+0200}, author = {Das, Atanu Kumar and Sarkar, Biprajit and Duboc, Carole and Strobel, Sabine and Fiedler, Jan and Zalis, Stanislav and Lahiri, Goutam Kumar and Kaim, Wolfgang}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d9914b9456b8bcf6c43a95c408737b55/b_schwederski}, interhash = {c6861d905bbb054759a66ba0689833a9}, intrahash = {d9914b9456b8bcf6c43a95c408737b55}, issn = {1521-3773}, journal = {Angewandte Chemie (International ed. in English)}, keywords = {imported}, number = 23, pages = {4242--4245}, timestamp = {2019-07-15T11:42:10.000+0200}, title = {An odd-electron complex [Ru(k)(NO(m))(Q(n))(terpy)]2+ with two prototypical non-innocent ligands}, volume = 48, year = 2009 }