Six combinations of oxidn. states are conceivable for the paramagnetic Ruk(NOm)(Qn)(terpy)2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: Ruk(NOm)(Qn)(terpy)2+ (k=2+, m=1+, n=1-). on SciFinder(R)
%0 Journal Article
%1 Das.2009b
%A Das, Atanu Kumar
%A Sarkar, Biprajit
%A Duboc, Carole
%A Strobel, Sabine
%A Fiedler, Jan
%A Zalis, Stanislav
%A Lahiri, Goutam Kumar
%A Kaim, Wolfgang.
%D 2009
%J Angewandte Chemie, International Edition
%K complex complex;cyclic complex;electronic complex;optimized complex;ruthenium crystal geometry iminobenzoquinone isomeric nitrosyl prepn ruthenium structure terpyridine voltammetry
%N 23
%P 4242-4245, S4242/1-S4242/6
%R 10.1002/anie.200900767
%T An Odd-Electron Complex Ruk(NOm)(Qn)(terpy)2+ with Two Prototypical Non-Innocent Ligands
%V 48
%X Six combinations of oxidn. states are conceivable for the paramagnetic Ruk(NOm)(Qn)(terpy)2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: Ruk(NOm)(Qn)(terpy)2+ (k=2+, m=1+, n=1-). on SciFinder(R)
@article{Das.2009b,
abstract = {Six combinations of oxidn. states are conceivable for the paramagnetic [Ruk(NOm)(Qn)(terpy)]2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: [Ruk(NOm)(Qn)(terpy)]2+ (k=2+, m=1+, n=1-). [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Das, Atanu Kumar and Sarkar, Biprajit and Duboc, Carole and Strobel, Sabine and Fiedler, Jan and Zalis, Stanislav and Lahiri, Goutam Kumar and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d22407d0afc5f3452c1570c14b9c094c/b_schwederski},
doi = {10.1002/anie.200900767},
interhash = {c6861d905bbb054759a66ba0689833a9},
intrahash = {d22407d0afc5f3452c1570c14b9c094c},
issn = {1433-7851},
journal = {Angewandte Chemie, International Edition},
keywords = {complex complex;cyclic complex;electronic complex;optimized complex;ruthenium crystal geometry iminobenzoquinone isomeric nitrosyl prepn ruthenium structure terpyridine voltammetry},
number = 23,
pages = {4242-4245, S4242/1-S4242/6},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands},
volume = 48,
year = 2009
}
