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An Odd-Electron Complex Ruk(NOm)(Qn)(terpy)2+ with Two Prototypical Non-Innocent Ligands

, , , , , , , and . Angewandte Chemie, International Edition 48 (23): 4242-4245, S4242/1-S4242/6 (2009)

Abstract

Six combinations of oxidn. states are conceivable for the paramagnetic Ruk(NOm)(Qn)(terpy)2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: Ruk(NOm)(Qn)(terpy)2+ (k=2+, m=1+, n=1-). on SciFinder(R)

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DOI:
10.1002/anie.200900767
BibTeX key:
Das.2009b
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