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New sulfide-bridged heterocubanes MVI(S)ReI3(CO)9(m3-S)4-, M = Mo or W, with transition metals in very different oxidation states

, , und . Chemical Communications (Cambridge, United Kingdom) (1998)

Zusammenfassung

(NEt4)MVI(S)ReI3(CO)9(m3-S)4 (M = Mo, W) were prepd. and found to contain 3 6-coordinate tricarbonylrhenium(I) fragments, held together by 1 m3-sulfide ion and by 1 reducible and charge transfer-active m3-MVIS42- unit. Crystal data are reported in space group P21/n for the isomorphic complex salts. UV-visible spectra including metal-metal charge transfer is discussed. on SciFinder(R)

Links und Ressourcen

DOI:
10.1039/a805295f
BibTeX-Schlüssel:
Hornung.1998c
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