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Substituent effects and perturbation of p systems, XXXV. Radical anions of tin-substituted naphthalenes

, , and . Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 33B (11): 1223--1226 (1978)

Abstract

Novel radical anions of trimethylstannyl substituted naphthalenes and their ESR spectra are reported. Both 119Sn and 117Sn coupling can be assigned unequivocally. The perturbation of p systems by R3X substituents of group IVA elements X = C, Si, Ge, Sn and Pb is discussed with respect to photoelectron ionization potentials, charge transfer excitations, half-wave redn. potentials and ESR spin distribution. on SciFinder(R)

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