%0 Journal Article %1 ISI:000369852200056 %A Alt, Isabel T. %A Plietker, Bernd %C POSTFACH 101161, 69451 WEINHEIM, GERMANY %D 2016 %I WILEY-V C H VERLAG GMBH %J ANGEWANDTE CHEMIE-INTERNATIONAL EDITION %K carbazoles; catalysis; homogeneous indoles; iron} {azides; %N 4 %P 1519-1522 %R 10.1002/anie.201510045 %T Iron-Catalyzed Intramolecular C(sp(2))-H Amination %V 55 %X The nucleophilic iron complex Bu4NFe(CO)(3)-(NO) (TBAFe) catalyzes the direct intramolecular C-H amination of alpha-azidobiaryls and (azidoaryl) alkenes into the corresponding carbazoles and indoles, respectively, under mild conditions and with low catalyst loadings. These features and the broad functional-group tolerance render this method a particularly attractive alternative to established noblemetal-based procedures.

@article{ISI:000369852200056, abstract = {{The nucleophilic iron complex Bu4N{[}Fe(CO)(3)-(NO)] (TBA{[}Fe]) catalyzes the direct intramolecular C-H amination of alpha-azidobiaryls and (azidoaryl) alkenes into the corresponding carbazoles and indoles, respectively, under mild conditions and with low catalyst loadings. These features and the broad functional-group tolerance render this method a particularly attractive alternative to established noblemetal-based procedures.}}, added-at = {2017-05-18T11:32:12.000+0200}, address = {{POSTFACH 101161, 69451 WEINHEIM, GERMANY}}, affiliation = {{Plietker, B (Reprint Author), Univ Stuttgart, Inst Organ Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany. Alt, Isabel T.; Plietker, Bernd, Univ Stuttgart, Inst Organ Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany.}}, author = {Alt, Isabel T. and Plietker, Bernd}, author-email = {{bernd.plietker@oc.uni-stuttgart.de}}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29ef76630a114f066875c4ef020ebe91d/hermann}, doi = {{10.1002/anie.201510045}}, eissn = {{1521-3773}}, funding-acknowledgement = {{Landesgraduiertenstiftung Baden-Wurttemberg; Deutsche Forschungsgemeinschaft}}, funding-text = {{Financial support by the Landesgraduiertenstiftung Baden-Wurttemberg (Ph.D. grant for I.A.) and the Deutsche Forschungsgemeinschaft is gratefully acknowledged.}}, interhash = {bddb8c3b7131dc7dc5ddd74ab965c0e5}, intrahash = {9ef76630a114f066875c4ef020ebe91d}, issn = {{1433-7851}}, journal = {{ANGEWANDTE CHEMIE-INTERNATIONAL EDITION}}, keywords = {carbazoles; catalysis; homogeneous indoles; iron} {azides;}, keywords-plus = {{H BOND AMINATION; CLOKE-WILSON REARRANGEMENT; ARYL AZIDES; STYRYL AZIDES; RH-2(II)-CATALYZED SYNTHESIS; ALLYLIC SUBSTITUTIONS; SALT-FREE; ACTIVATION; FE; COMPLEXES}}, language = {{English}}, month = {{JAN 22}}, number = {{4}}, number-of-cited-references = {{50}}, pages = {{1519-1522}}, publisher = {{WILEY-V C H VERLAG GMBH}}, research-areas = {{Chemistry}}, times-cited = {{7}}, timestamp = {2017-05-18T09:32:12.000+0200}, title = {{Iron-Catalyzed Intramolecular C(sp(2))-H Amination}}, type = {{Article}}, volume = {{55}}, web-of-science-categories = {{Chemistry, Multidisciplinary}}, year = {{2016}} }