MX2L2 (M = Pd, Pt; L = di(1-naphthyl)methylarsine = Nap2AsMe and X = Cl, Br, I), M2Cl2(m-Cl)2L2, PdCl(S2CNEt2)L, Pd2Cl2(m-OAc)2L2 and MCl2(PR3)L (PR3 = PEt3, PPr3, PBu3, PMePh2) were prepd. These complexes were characterized by elemental analyses, IR, Raman, NMR (1H, 13C, 31P) and UV-visible spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The crystal structures of trans-PdCl2(PEt3)(Nap2AsMe) and of Pd(S2CNEt2)2, a follow-up product, were detd. The UV-visible spectra of MX2L2 complexes show a red shift on going from X = Cl to X = I. PdX2L2 and PtX2L2 are strongly luminescent in fluid soln. and in the solid at ambient temp. on SciFinder(R)
%0 Journal Article
%1 Phadnis.2005
%A Phadnis, Prasad P.
%A Jain, Vimal K.
%A Schurr, Thilo
%A Klein, Axel
%A Lissner, Falk
%A Schleid, Thomas
%A Kaim, Wolfgang.
%D 2005
%J Inorganica Chimica Acta
%K UV UV;palladium UV;platinum complex complex;naphthylarsine complexation crystal dithiocarbamate luminescence naphthylarsine palladium phosphine platinum prepn structure
%N 9
%P 2609--2617
%R 10.1016/j.ica.2005.03.026
%T Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)
%V 358
%X MX2L2 (M = Pd, Pt; L = di(1-naphthyl)methylarsine = Nap2AsMe and X = Cl, Br, I), M2Cl2(m-Cl)2L2, PdCl(S2CNEt2)L, Pd2Cl2(m-OAc)2L2 and MCl2(PR3)L (PR3 = PEt3, PPr3, PBu3, PMePh2) were prepd. These complexes were characterized by elemental analyses, IR, Raman, NMR (1H, 13C, 31P) and UV-visible spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The crystal structures of trans-PdCl2(PEt3)(Nap2AsMe) and of Pd(S2CNEt2)2, a follow-up product, were detd. The UV-visible spectra of MX2L2 complexes show a red shift on going from X = Cl to X = I. PdX2L2 and PtX2L2 are strongly luminescent in fluid soln. and in the solid at ambient temp. on SciFinder(R)
@article{Phadnis.2005,
abstract = {[MX2L2] (M = Pd, Pt; L = di(1-naphthyl)methylarsine = Nap2AsMe and X = Cl, Br, I), [M2Cl2(\textgreek{m}-Cl)2L2], [PdCl(S2CNEt2)L], [Pd2Cl2(\textgreek{m}-OAc)2L2] and [MCl2(PR3)L] (PR3 = PEt3, PPr3, PBu3, PMePh2) were prepd. These complexes were characterized by elemental analyses, IR, Raman, NMR (1H, 13C, 31P) and UV-visible spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The crystal structures of trans-[PdCl2(PEt3)(Nap2AsMe)] and of [Pd(S2CNEt2)2], a follow-up product, were detd. The UV-visible spectra of [MX2L2] complexes show a red shift on going from X = Cl to X = I. [PdX2L2] and [PtX2L2] are strongly luminescent in fluid soln. and in the solid at ambient temp. [on SciFinder(R)]},
added-at = {2018-08-09T10:59:25.000+0200},
author = {Phadnis, Prasad P. and Jain, Vimal K. and Schurr, Thilo and Klein, Axel and Lissner, Falk and Schleid, Thomas and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29058cec634c92e51a8cdacc033274297/galaktoze},
doi = {10.1016/j.ica.2005.03.026},
interhash = {2dffff3970959f72522f45c5caa2d96d},
intrahash = {9058cec634c92e51a8cdacc033274297},
issn = {0020-1693},
journal = {Inorganica Chimica Acta},
keywords = {UV UV;palladium UV;platinum complex complex;naphthylarsine complexation crystal dithiocarbamate luminescence naphthylarsine palladium phosphine platinum prepn structure},
number = 9,
pages = {2609--2617},
timestamp = {2018-08-09T13:02:07.000+0200},
title = {Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)},
volume = 358,
year = 2005
}