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Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals

, , , , , , , , , und . Chemical Communications (Cambridge, United Kingdom) 53 (76): 10516--10519 (2017)

Zusammenfassung

Two cyclic (alkyl)(amino)carbene (cAAC) stabilized mononuclear neutral radicals of aluminum, (cAAC)2Al(Et)R (cAAC = 1-Dipp-3,3,5,5-tetramethyl-2-pyrrolidinylidene; 1, 2; R = Et, Cl) have been synthesized by reaction of cAAC with EtAlRCl and KC8. Compds. 1 and 2 are monoradicals, which were confirmed by EPR measurements to have the spin located on the carbene carbon of one of the cAAC ligands. on SciFinder(R)

Links und Ressourcen

DOI:
10.1039/C7CC06358J
BibTeX-Schlüssel:
Kundu.2017b
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