Cis-PdCl2Te(CH2CH2NMe2)2, synthesized by the reaction of Na2PdCl4 with Te(CH2CH2NMe2)2 in MeOH, contains an N,Te-chelated PdII center with a distorted square-planar coordination geometry. The Pd-Cl bond lengths are rather different at 2.2965(14) \AA (Cl trans to N) and 2.3888(12) \AA (Cl trans to Te); the Pd-Te bond is relatively short at 2.5078(6) \AA. One 2-dimethylaminoethyl substituent at Te remains uncoordinated. on SciFinder(R)
%0 Journal Article
%1 Dey.2004c
%A Dey, Sandip
%A Jain, Vimal K.
%A Knoedler, Axel
%A Kaim, Wolfgang.
%D 2004
%J X-Ray Structure Analysis Online
%K aminoethyltellurium chelate crystal palladium prepn structure
%N July-Sept
%P x127-x128
%T Synthesis and crystal structure of cis-dichlorobis(N,N-dimethylaminoethyl)tellurium-κ2N,Tepalladium(II)
%V 20
%X Cis-PdCl2Te(CH2CH2NMe2)2, synthesized by the reaction of Na2PdCl4 with Te(CH2CH2NMe2)2 in MeOH, contains an N,Te-chelated PdII center with a distorted square-planar coordination geometry. The Pd-Cl bond lengths are rather different at 2.2965(14) \AA (Cl trans to N) and 2.3888(12) \AA (Cl trans to Te); the Pd-Te bond is relatively short at 2.5078(6) \AA. One 2-dimethylaminoethyl substituent at Te remains uncoordinated. on SciFinder(R)
@article{Dey.2004c,
abstract = {Cis-[PdCl2{Te(CH2CH2NMe2)2}], synthesized by the reaction of Na2PdCl4 with Te(CH2CH2NMe2)2 in MeOH, contains an N,Te-chelated PdII center with a distorted square-planar coordination geometry. The Pd-Cl bond lengths are rather different at 2.2965(14) {\AA} (Cl trans to N) and 2.3888(12) {\AA} (Cl trans to Te); the Pd-Te bond is relatively short at 2.5078(6) {\AA}. One 2-dimethylaminoethyl substituent at Te remains uncoordinated. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Dey, Sandip and Jain, Vimal K. and Knoedler, Axel and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/273f7dd244dac0ebc278954a85606ba7a/b_schwederski},
interhash = {34aa384370b60601a9a6a6d93e51365b},
intrahash = {73f7dd244dac0ebc278954a85606ba7a},
journal = {X-Ray Structure Analysis Online},
keywords = {aminoethyltellurium chelate crystal palladium prepn structure},
number = {July-Sept},
pages = {x127-x128},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Synthesis and crystal structure of cis-dichloro{bis(N,N-dimethylaminoethyl)tellurium-κ2N,Te}palladium(II)},
volume = 20,
year = 2004
}