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Tetrathiorhenate(VI), ReS42-. Spectroelectrochemical characterization (UV-visible-IR) of a small new d1 system and of its tetrakis(2,2'-bipyridine)diruthenium(II) complex (EPR)

, , , and . Journal of the Chemical Society, Chemical Communications (1992)

Abstract

ReS42- is the first d1 tetrathiometalate persistent enough to be studied with respect to charge transfer, ligand field and IR vibrational spectra via spectroelectrochem.; an EPR spectrum could only be detected of its trinuclear deriv. (bpy)2Ru(m-ReS4)Ru(bpy)22+ (bpy = 2,2'-bipyridine) at 4 K. on SciFinder(R)

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DOI:
10.1039/C39920000834
BibTeX key:
Schafer.1992
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