The reaction of the ambidentate ligand 1,3-bis(3-methylpyridin-2-yl)thiourea (1) with PtCl2(dmso)2 in dichloromethane led to formation of a poorly soluble compound 2, characterized as a conventional chelate complex PtCl2(1) = 2. Reaction in methanol resulted in desulfurization to produce a fluorescing cationic diaminocarbene-platinum(II) complex 3, the structure of which was elucidated by x-ray crystallog., mass spectrometry and NMR. Exptl. findings were supported by DFT calculations
%0 Journal Article
%1 Bulak.2021
%A Bulak, Ece
%A Dogan, Ilknur
%A Varnali, Tereza
%A Schwederski, Brigitte
%A Gunal, Sule Erol
%A Lonnecke, Peter
%A Bubrin, Martina
%A Kaim, Wolfgang
%D 2021
%J European Journal of Inorganic Chemistry
%K imported
%N 24
%P 2425-2432
%R 10.1002/ejic.202100277
%T An Acyclic Diaminocarbene Complex of Platinum Formed by Desulfurization of 1,3-Bis(3-methylpyridin-2-yl)thiourea
%V 2021
%X The reaction of the ambidentate ligand 1,3-bis(3-methylpyridin-2-yl)thiourea (1) with PtCl2(dmso)2 in dichloromethane led to formation of a poorly soluble compound 2, characterized as a conventional chelate complex PtCl2(1) = 2. Reaction in methanol resulted in desulfurization to produce a fluorescing cationic diaminocarbene-platinum(II) complex 3, the structure of which was elucidated by x-ray crystallog., mass spectrometry and NMR. Exptl. findings were supported by DFT calculations
@article{Bulak.2021,
abstract = {The reaction of the ambidentate ligand 1,3-bis(3-methylpyridin-2-yl)thiourea (1) with [PtCl2(dmso)2] in dichloromethane led to formation of a poorly soluble compound 2, characterized as a conventional chelate complex [PtCl2(1)] = 2. Reaction in methanol resulted in desulfurization to produce a fluorescing cationic diaminocarbene-platinum(II) complex 3, the structure of which was elucidated by x-ray crystallog., mass spectrometry and NMR. Exptl. findings were supported by DFT calculations},
added-at = {2022-06-15T12:05:25.000+0200},
author = {Bulak, Ece and Dogan, Ilknur and Varnali, Tereza and Schwederski, Brigitte and Gunal, Sule Erol and Lonnecke, Peter and Bubrin, Martina and Kaim, Wolfgang},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/246ac01885a5be38bbf903feaec9380b1/huebleriac},
doi = {10.1002/ejic.202100277},
interhash = {b5a216d8e8f9b2d5ebdd80b9c40f6d3b},
intrahash = {46ac01885a5be38bbf903feaec9380b1},
issn = {1434-1948},
journal = {European Journal of Inorganic Chemistry},
keywords = {imported},
number = 24,
pages = {2425-2432},
timestamp = {2022-06-15T10:05:25.000+0200},
title = {An Acyclic Diaminocarbene Complex of Platinum Formed by Desulfurization of 1,3-Bis(3-methylpyridin-2-yl)thiourea},
volume = 2021,
year = 2021
}