Bridging the fields of organometallic and classical coordination chemistry: Localized and delocalized bonding in polynuclear complexes of (C5R5)(CO)2Mn
A review contg. 37 refs. The capability of the title fragment to undergo efficient p back bonding, to exist in two kinetically stable neighboring oxidn. states, and to exhibit a relatively small ligand field splitting allow the formation of unusual coordination compds. Several mono- and polynuclear examples with an odd or even electron count and different degrees and direction of electron delocalization between ligand and metal fragment(s) are discussed. on SciFinder(R)
%0 Journal Article
%1 Kaim.1988
%A Kaim, Wolfgang
%A Gross, Renate.
%D 1988
%J Comments on Inorganic Chemistry
%K chem complex coordination organometallic polynuclear review
%N 5
%P 269--285
%R 10.1080/02603598808072312
%T Bridging the fields of organometallic and classical coordination chemistry: Localized and delocalized bonding in polynuclear complexes of (C5R5)(CO)2Mn
%V 7
%X A review contg. 37 refs. The capability of the title fragment to undergo efficient p back bonding, to exist in two kinetically stable neighboring oxidn. states, and to exhibit a relatively small ligand field splitting allow the formation of unusual coordination compds. Several mono- and polynuclear examples with an odd or even electron count and different degrees and direction of electron delocalization between ligand and metal fragment(s) are discussed. on SciFinder(R)
@article{Kaim.1988,
abstract = {A review contg. 37 refs. The capability of the title fragment to undergo efficient \textgreek{p} back bonding, to exist in two kinetically stable neighboring oxidn. states, and to exhibit a relatively small ligand field splitting allow the formation of unusual coordination compds. Several mono- and polynuclear examples with an odd or even electron count and different degrees and direction of electron delocalization between ligand and metal fragment(s) are discussed. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Kaim, Wolfgang and Gross, Renate.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/232523a2c17e541c15fcc905c598033e0/b_schwederski},
doi = {10.1080/02603598808072312},
interhash = {c03969c32ea0a8c782860cbf45d7a7f5},
intrahash = {32523a2c17e541c15fcc905c598033e0},
issn = {0260-3594},
journal = {Comments on Inorganic Chemistry},
keywords = {chem complex coordination organometallic polynuclear review},
number = 5,
pages = {269--285},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Bridging the fields of organometallic and classical coordination chemistry: Localized and delocalized bonding in polynuclear complexes of (C5R5)(CO)2Mn},
volume = 7,
year = 1988
}
