Zusammenfassung

(NEt4)(acac)2RuS2ReS2Ru(acac)2 was characterized by cyclic voltammetry to reveal reversible redn. and oxidn. behavior. While the redox products proved EPR silent, the UV-visible-NIR spectroelectrochem. showed shifted charge-transfer absorptions and a typical near-IR intervalence (RuII $\rightarrow$ RuIII) band at lmax = 1725 nm (e = 1800 M-1 cm-1) for the 1-electron oxidized intermediate. The results are discussed in comparison to those obtained for (bpy)2RuS2ReS2Ru(bpy)2Cl3. on SciFinder(R)

Links und Ressourcen

DOI:
10.1016/j.poly.2014.05.016
BibTeX-Schlüssel:
Grupp.2015
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