Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand
A unique kind of electronic structure (Mn+0.5)(m-L.bul.-)(Mn+0.5) which was previously discussed only for metal-ligand charge-transfer (MLCT) excited states is established structurally and by quantum chem. anal. for both rac and meso isomers of (m-abpy)Ru(acac)22 (abpy = 2,2'-azobispyridine, acac- = acetylacetonate). on SciFinder(R)
%0 Journal Article
%1 Sarkar.2005
%A Sarkar, Biprajit
%A Patra, Srikanta
%A Fiedler, Jan
%A Sunoj, Raghavan B.
%A Janardanan, Deepa
%A Mobin, Shaikh M.
%A Niemeyer, Mark
%A Lahiri, Goutam Kumar
%A Kaim, Wolfgang.
%D 2005
%J Angewandte Chemie, International Edition
%K acetylacetonate azobispyridine complex complex;electrochem complex;electronic complex;geometry complex;ruthenium crystal isomeric optimized prepn redox ruthenium structure
%N 35
%P 5655--5658
%R 10.1002/anie.200501075
%T Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand
%V 44
%X A unique kind of electronic structure (Mn+0.5)(m-L.bul.-)(Mn+0.5) which was previously discussed only for metal-ligand charge-transfer (MLCT) excited states is established structurally and by quantum chem. anal. for both rac and meso isomers of (m-abpy)Ru(acac)22 (abpy = 2,2'-azobispyridine, acac- = acetylacetonate). on SciFinder(R)
@article{Sarkar.2005,
abstract = {A unique kind of electronic structure (Mn+0.5)(\textgreek{m}-L.bul.-)(Mn+0.5) which was previously discussed only for metal-ligand charge-transfer (MLCT) excited states is established structurally and by quantum chem. anal. for both rac and meso isomers of [(\textgreek{m}-abpy){Ru(acac)2}2] (abpy = 2,2'-azobispyridine, acac- = acetylacetonate). [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Sarkar, Biprajit and Patra, Srikanta and Fiedler, Jan and Sunoj, Raghavan B. and Janardanan, Deepa and Mobin, Shaikh M. and Niemeyer, Mark and Lahiri, Goutam Kumar and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21119c8287c8cf0cb9a8cb36e6e848187/b_schwederski},
doi = {10.1002/anie.200501075},
interhash = {e39395987a9d0f9479aa721991aaa134},
intrahash = {1119c8287c8cf0cb9a8cb36e6e848187},
issn = {1433-7851},
journal = {Angewandte Chemie, International Edition},
keywords = {acetylacetonate azobispyridine complex complex;electrochem complex;electronic complex;geometry complex;ruthenium crystal isomeric optimized prepn redox ruthenium structure},
number = 35,
pages = {5655--5658},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand},
volume = 44,
year = 2005
}
