Benzo-1,3,2-diselenazolylium chloride (I) was prepd. in 84\% yield by the reaction of 2-ClSeC6H4SeCl with Me3SiN3 in CH2Cl2. The cation has been characterized as its perchlorate by x-ray structure anal. Redn. via the unstable neutral radical state finally affords the nitrogen-free dibenzotetraselenocine. on SciFinder(R)
%0 Journal Article
%1 Wolmershaeuser.1992
%A Wolmershaeuser, Gotthelf
%A Kaim, Wolfgang
%A Heckmann, Gert
%A Lichtblau, Alexander.
%D 1992
%J Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences
%K benzodiselenazolylium crystal mol prepn salt structure;dibenzotetraselenocine;diselenazolylium structure;redn
%N 5
%P 675--679
%R 10.1515/znb-1992-0511
%T Benzo-1,3,2-diselenazolylium salts: Synthesis and reactivity
%V 47
%X Benzo-1,3,2-diselenazolylium chloride (I) was prepd. in 84\% yield by the reaction of 2-ClSeC6H4SeCl with Me3SiN3 in CH2Cl2. The cation has been characterized as its perchlorate by x-ray structure anal. Redn. via the unstable neutral radical state finally affords the nitrogen-free dibenzotetraselenocine. on SciFinder(R)
@article{Wolmershaeuser.1992,
abstract = {Benzo-1,3,2-diselenazolylium chloride (I) was prepd. in 84{\%} yield by the reaction of 2-ClSeC6H4SeCl with Me3SiN3 in CH2Cl2. The cation has been characterized as its perchlorate by x-ray structure anal. Redn. via the unstable neutral radical state finally affords the nitrogen-free dibenzotetraselenocine. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Wolmershaeuser, Gotthelf and Kaim, Wolfgang and Heckmann, Gert and Lichtblau, Alexander.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/200b751269876e4ceeb9e8c22b67d2fc1/b_schwederski},
doi = {10.1515/znb-1992-0511},
interhash = {6cc92ac1ea086823d772ebe2068f0259},
intrahash = {00b751269876e4ceeb9e8c22b67d2fc1},
issn = {0932-0776},
journal = {Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences},
keywords = {benzodiselenazolylium crystal mol prepn salt structure;dibenzotetraselenocine;diselenazolylium structure;redn},
number = 5,
pages = {675--679},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Benzo-1,3,2-diselenazolylium salts: Synthesis and reactivity},
volume = 47,
year = 1992
}