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Benzo-1,3,2-diselenazolylium salts: Synthesis and reactivity

, , , and . Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 47 (5): 675--679 (1992)
DOI: 10.1515/znb-1992-0511

Abstract

Benzo-1,3,2-diselenazolylium chloride (I) was prepd. in 84\% yield by the reaction of 2-ClSeC6H4SeCl with Me3SiN3 in CH2Cl2. The cation has been characterized as its perchlorate by x-ray structure anal. Redn. via the unstable neutral radical state finally affords the nitrogen-free dibenzotetraselenocine. on SciFinder(R)

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