%0 Journal Article %1 Bessenbacher.1989d %A Bessenbacher, Christian %A Kaim, Wolfgang. %D 1989 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K acetylpyrazine carbonyl carbonylpyrazine complex complex;cyclic complex;lumazine complex;lumiflavine complex;pyrazinecarboxamide complex;riboflavin rhenium voltammetry %P 39--52 %T Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands %V 577 %X Re(CO)3ClL (L = pyrazine-2-dimethylcarboxamide, 1-ethylpyrazinium-3-dimethylcarboxamide, 1,3-dimethyllumazine, 2,5-diacetylpyrazine, lumiflavine and riboflavin were prepd. and studied by cyclic voltammetry and spectroscopy (IR, electronic, ESR). s-Polarization and p-back-bonding by the organometallic fragment cause stabilization of the reduced (radical) form and of the first metal-to-ligand charge transfer excited state. on SciFinder(R)

@article{Bessenbacher.1989d, abstract = {Re(CO)3ClL (L = pyrazine-2-dimethylcarboxamide, 1-ethylpyrazinium-3-dimethylcarboxamide, 1,3-dimethyllumazine, 2,5-diacetylpyrazine, lumiflavine and riboflavin were prepd. and studied by cyclic voltammetry and spectroscopy (IR, electronic, ESR). \textgreek{s}-Polarization and \textgreek{p}-back-bonding by the organometallic fragment cause stabilization of the reduced (radical) form and of the first metal-to-ligand charge transfer excited state. [on SciFinder(R)]}, added-at = {2019-07-15T13:41:23.000+0200}, author = {Bessenbacher, Christian and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2c21363501353bcb3b0a561b5fbe797de/b_schwederski}, interhash = {c7cfcf5f81a4d8adc2620fc7568f217b}, intrahash = {c21363501353bcb3b0a561b5fbe797de}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {acetylpyrazine carbonyl carbonylpyrazine complex complex;cyclic complex;lumazine complex;lumiflavine complex;pyrazinecarboxamide complex;riboflavin rhenium voltammetry}, pages = {39--52}, timestamp = {2019-07-15T11:42:10.000+0200}, title = {Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands}, volume = 577, year = 1989 }