A review with $\sim$60 refs. Transition metal complexes contg. anion radical ligands display a strong tendency towards full coordinative satn. at the singly reduced ligand and towards substitutional activation of co-ligands at the metal center. Examples involving metal carbonyls show how both of these reactivities can be employed either sep. or in a combined fashion for electron transfer catalyzed substitution processes and for the construction of new polynuclear complexes with unusual properties. on SciFinder(R)
%0 Journal Article
%1 Kaim.1989c
%A Kaim, Wolfgang
%A Olbrich-Deussner, Barbara
%A Gross, Renate
%A Ernst, Sylvia
%A Kohlmann, Stephan
%A Bessenbacher, Christian.
%D 1989
%J NATO ASI Series, Series C: Mathematical and Physical Sciences
%K anion complex electron formation metal reaction review;polynuclear review;review transfer transition
%N Paramagn. Organomet. Species Act./Sel., Catal
%P 283--294
%T Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes
%V 257
%X A review with $\sim$60 refs. Transition metal complexes contg. anion radical ligands display a strong tendency towards full coordinative satn. at the singly reduced ligand and towards substitutional activation of co-ligands at the metal center. Examples involving metal carbonyls show how both of these reactivities can be employed either sep. or in a combined fashion for electron transfer catalyzed substitution processes and for the construction of new polynuclear complexes with unusual properties. on SciFinder(R)
@article{Kaim.1989c,
abstract = {A review with $\sim$60 refs. Transition metal complexes contg. anion radical ligands display a strong tendency towards full coordinative satn. at the singly reduced ligand and towards substitutional activation of co-ligands at the metal center. Examples involving metal carbonyls show how both of these reactivities can be employed either sep. or in a combined fashion for electron transfer catalyzed substitution processes and for the construction of new polynuclear complexes with unusual properties. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang and Olbrich-Deussner, Barbara and Gross, Renate and Ernst, Sylvia and Kohlmann, Stephan and Bessenbacher, Christian.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d9b2eacfb70d51cf19987cbb9aa7f194/huebleriac},
interhash = {af06063666b48fcbd9e5e63f1129de8a},
intrahash = {d9b2eacfb70d51cf19987cbb9aa7f194},
issn = {0258-2023},
journal = {NATO ASI Series, Series C: Mathematical and Physical Sciences},
keywords = {anion complex electron formation metal reaction review;polynuclear review;review transfer transition},
number = {Paramagn. Organomet. Species Act./Sel., Catal},
pages = {283--294},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes},
volume = 257,
year = 1989
}
