The compds. [W(CO)5(btd)], [W(CO)5(bsd] and [Re(CO)3(bpy)(bsd)](BF4), btd=2,1,3-benzothiadiazole and bsd=2,1,3-benzoselenadiazole were isolated and characterized exptl. (crystal structure, spectroscopy, spectroelectrochem.) and by d. functional theory calcns. The results confirm single N-coordination in all cases, binding to Se was calcd. to be less favorable. Studies of one-electron reduced forms indicate that the N-coordination is maintained during electron transfer. [on SciFinder(R)]
%0 Journal Article
%1 Plebst.2017
%A Plebst, Sebastian
%A Bubrin, Martina
%A Schweinfurth, David
%A Zalis, Stanislav
%A Kaim, Wolfgang.
%D 2017
%J Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences
%K imported
%N 11
%P 839--846
%R 10.1515/znb-2017-0100
%T Metal carbonyl complexes of potentially ambidentate 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole acceptors
%V 72
%X The compds. [W(CO)5(btd)], [W(CO)5(bsd] and [Re(CO)3(bpy)(bsd)](BF4), btd=2,1,3-benzothiadiazole and bsd=2,1,3-benzoselenadiazole were isolated and characterized exptl. (crystal structure, spectroscopy, spectroelectrochem.) and by d. functional theory calcns. The results confirm single N-coordination in all cases, binding to Se was calcd. to be less favorable. Studies of one-electron reduced forms indicate that the N-coordination is maintained during electron transfer. [on SciFinder(R)]
@article{Plebst.2017,
abstract = {The compds. [W(CO)5(btd)], [W(CO)5(bsd] and [Re(CO)3(bpy)(bsd)](BF4), btd=2,1,3-benzothiadiazole and bsd=2,1,3-benzoselenadiazole were isolated and characterized exptl. (crystal structure, spectroscopy, spectroelectrochem.) and by d. functional theory calcns. The results confirm single N-coordination in all cases, binding to Se was calcd. to be less favorable. Studies of one-electron reduced forms indicate that the N-coordination is maintained during electron transfer. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Plebst, Sebastian and Bubrin, Martina and Schweinfurth, David and Zalis, Stanislav and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2825f7c875efc2b8e936a68f217089ce9/huebleriac},
doi = {10.1515/znb-2017-0100},
interhash = {a4e1db1d3dbb0f1e34b74e6bfc659e4c},
intrahash = {825f7c875efc2b8e936a68f217089ce9},
issn = {0932-0776},
journal = {Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences},
keywords = {imported},
number = 11,
pages = {839--846},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Metal carbonyl complexes of potentially ambidentate 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole acceptors},
volume = 72,
year = 2017
}
