protection of the axial positions of square-planar platinum(II) center of (2,2'-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III)
A. Klein, H. Hausen, and W. Kaim. Journal of Organometallic Chemistry, 440 (1-2):
207--217(1992)
Abstract
The mol. structure of (2,2'-bipyridine)dimesitylplatinum as detd. by x-ray diffraction reveals efficient protection of the axial positions of the essentially square-planar platinum(II) center. The chem. consequences include a strongly diminished propensity towards oxidative addn. and the electrochem. reversible oxidn. at about +0.4 V vs. Fc/Fc+ to a reactive Pt(III) cation. In conjunction with the MLCT absorption and emission energies and the potential for reversible redn. to an anion radical complex, the contributions from intra- and intermol. reorganization could be reliably detd. on SciFinder(R)
%0 Journal Article
%1 Klein.1992
%A Klein, Axel
%A Hausen, Hans-Dieter
%A Kaim, Wolfgang.
%D 1992
%J Journal of Organometallic Chemistry
%K bipyridine crystal dimesityl platinum platinum;Luminescence platinum;electrochem platinum;mol redox structure
%N 1-2
%P 207--217
%T protection of the axial positions of square-planar platinum(II) center of (2,2'-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III)
%V 440
%X The mol. structure of (2,2'-bipyridine)dimesitylplatinum as detd. by x-ray diffraction reveals efficient protection of the axial positions of the essentially square-planar platinum(II) center. The chem. consequences include a strongly diminished propensity towards oxidative addn. and the electrochem. reversible oxidn. at about +0.4 V vs. Fc/Fc+ to a reactive Pt(III) cation. In conjunction with the MLCT absorption and emission energies and the potential for reversible redn. to an anion radical complex, the contributions from intra- and intermol. reorganization could be reliably detd. on SciFinder(R)
@article{Klein.1992,
abstract = {The mol. structure of (2,2'-bipyridine)dimesitylplatinum as detd. by x-ray diffraction reveals efficient protection of the axial positions of the essentially square-planar platinum(II) center. The chem. consequences include a strongly diminished propensity towards oxidative addn. and the electrochem. reversible oxidn. at about +0.4 V vs. Fc/Fc+ to a reactive Pt(III) cation. In conjunction with the MLCT absorption and emission energies and the potential for reversible redn. to an anion radical complex, the contributions from intra- and intermol. reorganization could be reliably detd. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Klein, Axel and Hausen, Hans-Dieter and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/237fcb3b3a8bff55a38a1d9d7dab5b7e0/b_schwederski},
interhash = {9f53bc37fa0fd06956ebd5a46ba6a13b},
intrahash = {37fcb3b3a8bff55a38a1d9d7dab5b7e0},
journal = {Journal of Organometallic Chemistry},
keywords = {bipyridine crystal dimesityl platinum platinum;Luminescence platinum;electrochem platinum;mol redox structure},
number = {1-2},
pages = {207--217},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {protection of the axial positions of square-planar platinum(II) center of (2,2'-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III)},
volume = 440,
year = 1992
}