%0 Journal Article %1 Knoedler.2005 %A Knoedler, Axel %A Kaim, Wolfgang. %D 2005 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K DMSO chloro cis complex complex;electrochem complex;ruthenium crystal isomerism prepn redox ruthenium structure terpyridine trans %N 2-3 %P 491--495 %R 10.1002/zaac.200400330 %T Cis/trans-isomerism of complexes RuCl2(S-dmso)tpy), tpy = terpyridine ligand %V 631 %X The mol. structure of the precursor compd. trans-RuCl2(DMSO)(terpy) for Ru(terpy)2+ contg. complexes was detd. for the trihydrate (terpy = 2,2':6',2\dq-terpyridine) (triclinic, P1̅, a 8.6232(17), b 8.6723(17), c 14.274(3) \AA, a 93.09(3), b 94.69(3), g 108.18(3)°, Z = 2, dc = 1.772, 5436 independent reflections, 337 refined parameters, R1 = 0.0366, wR2 = 0.0844 ( I \textgreater 2s(I))). The mol. exhibits S-bonded DMSO with the S:O bond in the Ru(h3-terpy) plane and axially positioned chloride ligands. Electrochem. studies of the cis/trans reaction product mixt. in CH2Cl2 showed 2 oxidn. processes for the reversible Ru(II)/(III) transitions but irreversible redn. Only one reversible oxidn. wave and a uniform 1H-NMR spectrum were obsd. for the isolated product in case of the related RuCl2(dmso)(mtpy) (mtpy = 4'-(4-methylphenyl)-2,2':6',2\dq-terpyridine), the electrochem., NMR and S:O vibrational stretching values allowed us to identify this product as the trans isomer. on SciFinder(R)

@article{Knoedler.2005, abstract = {The mol. structure of the precursor compd. trans-[RuCl2(DMSO)(terpy)] for [Ru(terpy)]2+ contg. complexes was detd. for the trihydrate (terpy = 2,2':6',2{\dq}-terpyridine) (triclinic, P1̅, a 8.6232(17), b 8.6723(17), c 14.274(3) {\AA}, \textgreek{a} 93.09(3), \textgreek{b} 94.69(3), \textgreek{g} 108.18(3)°, Z = 2, dc = 1.772, 5436 independent reflections, 337 refined parameters, R1 = 0.0366, wR2 = 0.0844 ( I {\textgreater} 2\textgreek{s}(I))). The mol. exhibits S-bonded DMSO with the S:O bond in the Ru(\textgreek{h}3-terpy) plane and axially positioned chloride ligands. Electrochem. studies of the cis/trans reaction product mixt. in CH2Cl2 showed 2 oxidn. processes for the reversible Ru(II)/(III) transitions but irreversible redn. Only one reversible oxidn. wave and a uniform 1H-NMR spectrum were obsd. for the isolated product in case of the related [RuCl2(dmso)(mtpy)] (mtpy = 4'-(4-methylphenyl)-2,2':6',2{\dq}-terpyridine), the electrochem., NMR and S:O vibrational stretching values allowed us to identify this product as the trans isomer. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Knoedler, Axel and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2067937719638fe638b05913f07709e87/huebleriac}, doi = {10.1002/zaac.200400330}, interhash = {7ac9502b88c88f3395cd05e0c4625d48}, intrahash = {067937719638fe638b05913f07709e87}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {DMSO chloro cis complex complex;electrochem complex;ruthenium crystal isomerism prepn redox ruthenium structure terpyridine trans}, number = {2-3}, pages = {491--495}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Cis/trans-isomerism of complexes [RuCl2(S-dmso)tpy)], tpy = terpyridine ligand}, volume = 631, year = 2005 }