%0 Journal Article %1 Baumann.1999b %A Baumann, Frank %A Kaim, Wolfgang %A Baraldo, Luis M. %A Slep, Leonardo D. %A Olabe, Jose A. %A Fiedler, Jan. %D 1999 %J Inorganica Chimica Acta %K ESR complex cyano electrochem nitrosyl osmium prepn redn spectroelectrochem %N 1 %P 129--133 %R 10.1016/S0020-1693(98)00254-0 %T Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion %V 285 %X The reversible redn. of Os(CN)5(NO)2-, the osmium analog of the nitroprusside ion, was studied by spectroelectrochem. techniques (IR, UV-visible, EPR). The strong shift of the nitrosyl stretching band from 1850 to 1560 cm-1 (in acetonitrile) already indicates nitrosyl ligand-centered redn. in comparison to the smaller shifts for the cyanide frequencies (2140 $\rightarrow$ 2080 cm-1). Remarkably, the g factor anal. (g‖ = 2.017, g$\bot$ = 2.003) for electrogenerated Os(CN)5(NO)3- does not reflect any effect from the 5d element osmium with its high spin-orbit coupling const.; only the need to apply helium temps. for EPR signal observation indicates a heavy transition metal. on SciFinder(R)

@article{Baumann.1999b, abstract = {The reversible redn. of [Os(CN)5(NO)]2-, the osmium analog of the nitroprusside ion, was studied by spectroelectrochem. techniques (IR, UV-visible, EPR). The strong shift of the nitrosyl stretching band from 1850 to 1560 cm-1 (in acetonitrile) already indicates nitrosyl ligand-centered redn. in comparison to the smaller shifts for the cyanide frequencies (2140 $\rightarrow$ 2080 cm-1). Remarkably, the g factor anal. (g‖ = 2.017, g$\bot$ = 2.003) for electrogenerated [Os(CN)5(NO)]3- does not reflect any effect from the 5d element osmium with its high spin-orbit coupling const.; only the need to apply helium temps. for EPR signal observation indicates a heavy transition metal. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Baumann, Frank and Kaim, Wolfgang and Baraldo, Luis M. and Slep, Leonardo D. and Olabe, Jose A. and Fiedler, Jan.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27652c91f876d41af7ec16f588a406d09/huebleriac}, doi = {10.1016/S0020-1693(98)00254-0}, interhash = {65a3dea9aaf311b7c21c3ccadf863fbf}, intrahash = {7652c91f876d41af7ec16f588a406d09}, issn = {0020-1693}, journal = {Inorganica Chimica Acta}, keywords = {ESR complex cyano electrochem nitrosyl osmium prepn redn spectroelectrochem}, number = 1, pages = {129--133}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion}, volume = 285, year = 1999 }