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Interacting metal and ligand based open shell systems: Challenges for experiment and theory

, and . Coordination Chemistry Reviews, (2017)
DOI: 10.1016/j.ccr.2016.12.008

Abstract

Three-center bridged situations Ru-L-Ru and Q-M-Q (M = Ru, Co, Ni, Cu) contg. redox-active transition metals and noninnocently behaving ligand redox systems Lk or Qn (o-iminoquinone/o-iminosemiquinone/o-amidophenolate series) can provide valuable insight into electronic and spin interactions of correlated coordination compds. Exptl. approaches using combined structural, electrochem., spectroscopic (UV-vis-NIR) and magnetic resonance methods were employed with computational support to elucidate which of the potential alternatives are most appropriate to describe the individual electronic structures. [on SciFinder(R)]

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