%0 Journal Article %1 Klein.1999b %A Klein, Axel %A Scheiring, Thomas %A Kaim, Wolfgang. %D 1999 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K dipyridophenazine mesityl mol platinum structure %N 7 %P 1177--1180 %R 10.1002/(SICI)1521-3749(199907)625:7\textless1177::AID-ZAAC1177\textgreater3.0.CO;2-1 %T Molecular and crystal structure of an organoplatinum(II) complex with dipyrido3,2-a:2',3'-cphenazine (dppz) %V 625 %X PtMes2(dppz).toluene (Mes = mesityl) is monoclinic, space group P21/c, Z = 4, a 14.3551(14), b 15.8319(14), c 15.369(2) \AA, b 96.748(6)°, dc = 1.547, R = 0.0596, Fw = 0.1469 for 3755 reflections. The (dppz)PtC1Mes2 part of the mol. is planar, the mesityl substituents adopting dihedral angles of 70.3 and 85.5° with that plane. The photoemissive and reversibly reducible and oxidizable complex mols. form pairs in the crystal with the planar phenazine p tails overlapping in graphite-like fashion at 3.427 \AA distance. The results are discussed in comparison with a recently reported structure of PtCl2(dppz). on SciFinder(R)

@article{Klein.1999b, abstract = {PtMes2(dppz).toluene (Mes = mesityl) is monoclinic, space group P21/c, Z = 4, a 14.3551(14), b 15.8319(14), c 15.369(2) {\AA}, \textgreek{b} 96.748(6)°, dc = 1.547, R = 0.0596, Fw = 0.1469 for 3755 reflections. The (dppz)Pt[C1Mes]2 part of the mol. is planar, the mesityl substituents adopting dihedral angles of 70.3 and 85.5° with that plane. The photoemissive and reversibly reducible and oxidizable complex mols. form pairs in the crystal with the planar phenazine \textgreek{p} tails overlapping in graphite-like fashion at 3.427 {\AA} distance. The results are discussed in comparison with a recently reported structure of PtCl2(dppz). [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Klein, Axel and Scheiring, Thomas and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/26e0ec3271ad4efd5f013277dcfa8cb48/huebleriac}, doi = {10.1002/(SICI)1521-3749(199907)625:7{\textless}1177::AID-ZAAC1177{\textgreater}3.0.CO;2-1}, interhash = {46ec619097531e250f3aaf65440a7725}, intrahash = {6e0ec3271ad4efd5f013277dcfa8cb48}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {dipyridophenazine mesityl mol platinum structure}, number = 7, pages = {1177--1180}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Molecular and crystal structure of an organoplatinum(II) complex with dipyrido[3,2-a:2',3'-c]phenazine (dppz)}, volume = 625, year = 1999 }