Characterization of the inorganic/organometallic osmium(IV) compound Cp*2OsIVCl2OsIVCl6 as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air
T. Sixt, W. Kaim, and W. Preetz. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 55 (3/4):
235--237(2000)
Abstract
Reaction of OsCl3 with pentamethylcyclopentadiene in EtOH in air yields the ionic Os(IV) compd. Cp*2OsCl2OsCl6 which was identified structurally and by vibrational spectroscopy. Under comparable conditions the RuCl3 homolog yields the Ru(III) compd. Cp*RuCl22, illustrating the more facile oxidn. of the 5d element to the tetravalent state. on SciFinder(R)
%0 Journal Article
%1 Sixt.2000
%A Sixt, Torsten
%A Kaim, Wolfgang
%A Preetz, Wilhelm.
%D 2000
%J Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences
%K chloroosmate chloroosmate;pentamethylcyclopentadiene complexation crystal osmium pentamethylcyclopentadienyl prepn;mol structure trichloride
%N 3/4
%P 235--237
%T Characterization of the inorganic/organometallic osmium(IV) compound Cp*2OsIVCl2OsIVCl6 as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air
%V 55
%X Reaction of OsCl3 with pentamethylcyclopentadiene in EtOH in air yields the ionic Os(IV) compd. Cp*2OsCl2OsCl6 which was identified structurally and by vibrational spectroscopy. Under comparable conditions the RuCl3 homolog yields the Ru(III) compd. Cp*RuCl22, illustrating the more facile oxidn. of the 5d element to the tetravalent state. on SciFinder(R)
@article{Sixt.2000,
abstract = {Reaction of OsCl3 with pentamethylcyclopentadiene in EtOH in air yields the ionic Os(IV) compd. [Cp*2OsCl]2[OsCl6] which was identified structurally and by vibrational spectroscopy. Under comparable conditions the RuCl3 homolog yields the Ru(III) compd. [Cp*RuCl2]2, illustrating the more facile oxidn. of the 5d element to the tetravalent state. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Sixt, Torsten and Kaim, Wolfgang and Preetz, Wilhelm.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2bb445aa7d0f0686c7d004be1091cda66/b_schwederski},
interhash = {3df3ad72155d7f428293382695810b41},
intrahash = {bb445aa7d0f0686c7d004be1091cda66},
issn = {0932-0776},
journal = {Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences},
keywords = {chloroosmate chloroosmate;pentamethylcyclopentadiene complexation crystal osmium pentamethylcyclopentadienyl prepn;mol structure trichloride},
number = {3/4},
pages = {235--237},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Characterization of the inorganic/organometallic osmium(IV) compound [Cp*2OsIVCl]2[OsIVCl6] as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air},
volume = 55,
year = 2000
}