%0 Journal Article %1 Cotton.1981 %A Cotton, F. Albert %A Ilsley, William H. %A Kaim, Wolfgang. %D 1981 %J Inorganic Chemistry %K acetato mol molybdenum phenylacetamidinato;xylylacetamidinato structure %N 3 %P 930--934 %R 10.1021/ic50217a058 %T (Acetato)tris(N,N'-diphenylacetamidinato)dimolybdenum and bis(acetato)bis[N,N'-bis(2,6-xylyl)acetamidinato]dimolybdenum tetrakis(tetrahydrofuranate). Two new mixed-ligand quadruply bonded dimolybdenum compounds %V 20 %X Mo2[[(2,6-xylyl)N]2CCH3]2(CH3CO2)2.4THF is triclinic, space group P1̅, with a 11.637(2), b 11.655(1), c 11.824(2) \AA, a 90.82(1), b 108.75(1), and g 70.02(1)°; Z = 1. Each mol. has 2 axially coordinated THF mols. and resides on a center of inversion. The Mo-Mo bond length is 2.107(1) \AA, and the av. Mo-O(acetate) and Mo-N bond lengths are 2.107(4) and 2.162(5) \AA, resp. The Mo-O(THF) distance is 2.709(6) \AA. Mo2[(PhN)2CCH3]3(CH3CO2) is triclinic, space group P1̅, with a 12.516(3), b 17.968(4), c 10.214(2) \AA, a 93.88(2), b 113.17(2), and g 71.95(2)°; Z = 2. Each mol. occupies a general position within the unit cell. The Mo-Mo distance is 2.082(1) \AA, and the Mo-O distances av. $\sim$2.162(5) \AA and indicate the operation of a structural trans effect in the mol. [on SciFinder(R)]

@article{Cotton.1981, abstract = {Mo2[[(2,6-xylyl)N]2CCH3]2(CH3CO2)2.4THF is triclinic, space group P1̅, with a 11.637(2), b 11.655(1), c 11.824(2) {\AA}, \textgreek{a} 90.82(1), \textgreek{b} 108.75(1), and \textgreek{g} 70.02(1)°; Z = 1. Each mol. has 2 axially coordinated THF mols. and resides on a center of inversion. The Mo-Mo bond length is 2.107(1) {\AA}, and the av. Mo-O(acetate) and Mo-N bond lengths are 2.107(4) and 2.162(5) {\AA}, resp. The Mo-O(THF) distance is 2.709(6) {\AA}. Mo2[(PhN)2CCH3]3(CH3CO2) is triclinic, space group P1̅, with a 12.516(3), b 17.968(4), c 10.214(2) {\AA}, \textgreek{a} 93.88(2), \textgreek{b} 113.17(2), and \textgreek{g} 71.95(2)°; Z = 2. Each mol. occupies a general position within the unit cell. The Mo-Mo distance is 2.082(1) {\AA}, and the Mo-O distances av. $\sim$2.162(5) {\AA} and indicate the operation of a structural trans effect in the mol. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Cotton, F. Albert and Ilsley, William H. and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/22c0692f0e876fb28877aa98082d0d948/huebleriac}, doi = {10.1021/ic50217a058}, interhash = {366f29dc2b6bf7ce72bb063fa88175d5}, intrahash = {2c0692f0e876fb28877aa98082d0d948}, issn = {0020-1669}, journal = {Inorganic Chemistry}, keywords = {acetato mol molybdenum phenylacetamidinato;xylylacetamidinato structure}, number = 3, pages = {930--934}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {(Acetato)tris(N,N'-diphenylacetamidinato)dimolybdenum and bis(acetato)bis[N,N'-bis(2,6-xylyl)acetamidinato]dimolybdenum tetrakis(tetrahydrofuranate). Two new mixed-ligand quadruply bonded dimolybdenum compounds}, volume = 20, year = 1981 }