%0 Journal Article %1 Phadnis.2005 %A Phadnis, Prasad P. %A Jain, Vimal K. %A Schurr, Thilo %A Klein, Axel %A Lissner, Falk %A Schleid, Thomas %A Kaim, Wolfgang. %D 2005 %J Inorganica Chimica Acta %K UV UV;palladium UV;platinum complex complex;naphthylarsine complexation crystal dithiocarbamate luminescence naphthylarsine palladium phosphine platinum prepn structure %N 9 %P 2609--2617 %R 10.1016/j.ica.2005.03.026 %T Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II) %V 358 %X [MX2L2] (M = Pd, Pt; L = di(1-naphthyl)methylarsine = Nap2AsMe and X = Cl, Br, I), [M2Cl2(m-Cl)2L2], [PdCl(S2CNEt2)L], [Pd2Cl2(m-OAc)2L2] and [MCl2(PR3)L] (PR3 = PEt3, PPr3, PBu3, PMePh2) were prepd. These complexes were characterized by elemental analyses, IR, Raman, NMR (1H, 13C, 31P) and UV-visible spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The crystal structures of trans-[PdCl2(PEt3)(Nap2AsMe)] and of [Pd(S2CNEt2)2], a follow-up product, were detd. The UV-visible spectra of [MX2L2] complexes show a red shift on going from X = Cl to X = I. [PdX2L2] and [PtX2L2] are strongly luminescent in fluid soln. and in the solid at ambient temp. [on SciFinder(R)]

@article{Phadnis.2005, abstract = {[MX2L2] (M = Pd, Pt; L = di(1-naphthyl)methylarsine = Nap2AsMe and X = Cl, Br, I), [M2Cl2(\textgreek{m}-Cl)2L2], [PdCl(S2CNEt2)L], [Pd2Cl2(\textgreek{m}-OAc)2L2] and [MCl2(PR3)L] (PR3 = PEt3, PPr3, PBu3, PMePh2) were prepd. These complexes were characterized by elemental analyses, IR, Raman, NMR (1H, 13C, 31P) and UV-visible spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The crystal structures of trans-[PdCl2(PEt3)(Nap2AsMe)] and of [Pd(S2CNEt2)2], a follow-up product, were detd. The UV-visible spectra of [MX2L2] complexes show a red shift on going from X = Cl to X = I. [PdX2L2] and [PtX2L2] are strongly luminescent in fluid soln. and in the solid at ambient temp. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Phadnis, Prasad P. and Jain, Vimal K. and Schurr, Thilo and Klein, Axel and Lissner, Falk and Schleid, Thomas and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29058cec634c92e51a8cdacc033274297/huebleriac}, doi = {10.1016/j.ica.2005.03.026}, interhash = {2dffff3970959f72522f45c5caa2d96d}, intrahash = {9058cec634c92e51a8cdacc033274297}, issn = {0020-1693}, journal = {Inorganica Chimica Acta}, keywords = {UV UV;palladium UV;platinum complex complex;naphthylarsine complexation crystal dithiocarbamate luminescence naphthylarsine palladium phosphine platinum prepn structure}, number = 9, pages = {2609--2617}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)}, volume = 358, year = 2005 }