%0 Journal Article %1 Wiberg.1997 %A Wiberg, Nils %A Amelunxen, Kerstin %A Noth, Heinrich %A Schwenk, Holger %A Kaim, Wolfgang %A Klein, Axel %A Scheiring, Thomas. %D 1997 %J Angewandte Chemie, International Edition in English %K aluminum butylsilyl dinuclear gallium prepn prepn;crystal radical radical;ESR radical;gallium structure structure;silyl structure;supersilyl supersilyl %N 11 %P 1213--1215 %R 10.1002/anie.199712131 %T Compounds of silicon. 113. Sterically overloaded supersilyl compounds. 12. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: A new type of compound for a heavy Group 13 element %V 36 %X The reaction of GaCl3 with t-Bu3SiNa(THF)2 in a 1:3 molar ratio produces, in addn. to hexa-tert-butyldisilane and NaCl, the tris(tri-tert-butylsilyl)digallanyl radical (tBu3Si)3Ga2 (1). An intermediate reaction product is chlorodisupersilylgallane, (t-Bu3Si)2GaCl (2), which reacts with t-Bu3SiNa to give the postulated intermediate (t-Bu3Si)2GaGa(SiBu-t3)2 (3) which subsequently loses t-Bu3Si· to give 1. 1 Was characterized by x-ray crystallog. (monoclinic, space group C2/c, R1 = 0.0687) and ESR. The bond between the Ga atoms has a formal bond order of 1.5. The intermediate existence of 3 is supported by the reaction of AlCl3 etherate with t-Bu3SiNa which gives (t-Bu3Si)2AlCl and then (t-Bu3Si)2AlAl(SiBu-t3)2, which does not form the analogous Al radical of 1. on SciFinder(R)

@article{Wiberg.1997, abstract = {The reaction of GaCl3 with t-Bu3SiNa(THF)2 in a 1:3 molar ratio produces, in addn. to hexa-tert-butyldisilane and NaCl, the tris(tri-tert-butylsilyl)digallanyl radical (tBu3Si)3Ga2 (1). An intermediate reaction product is chlorodisupersilylgallane, (t-Bu3Si)2GaCl (2), which reacts with t-Bu3SiNa to give the postulated intermediate (t-Bu3Si)2GaGa(SiBu-t3)2 (3) which subsequently loses t-Bu3Si· to give 1. 1 Was characterized by x-ray crystallog. (monoclinic, space group C2/c, R1 = 0.0687) and ESR. The bond between the Ga atoms has a formal bond order of 1.5. The intermediate existence of 3 is supported by the reaction of AlCl3 etherate with t-Bu3SiNa which gives (t-Bu3Si)2AlCl and then (t-Bu3Si)2AlAl(SiBu-t3)2, which does not form the analogous Al radical of 1. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Wiberg, Nils and Amelunxen, Kerstin and Noth, Heinrich and Schwenk, Holger and Kaim, Wolfgang and Klein, Axel and Scheiring, Thomas.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2e49ff44598bf49b0e4c61bed83d35ba1/huebleriac}, doi = {10.1002/anie.199712131}, interhash = {12a7f13214006068568e5546ee6943d8}, intrahash = {e49ff44598bf49b0e4c61bed83d35ba1}, issn = {0570-0833}, journal = {Angewandte Chemie, International Edition in English}, keywords = {aluminum butylsilyl dinuclear gallium prepn prepn;crystal radical radical;ESR radical;gallium structure structure;silyl structure;supersilyl supersilyl}, number = 11, pages = {1213--1215}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Compounds of silicon. 113. Sterically overloaded supersilyl compounds. 12. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: A new type of compound for a heavy Group 13 element}, volume = 36, year = 1997 }