Article,

Synthesis and structure of bis(2-N,N-dimethylaminoethylselenolato)zinc and its transformation to ZnSe

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Polyhedron, 22 (4): 489--491 (2003)
DOI: 10.1016/S0277-5387(02)01379-7

Abstract

The crystal structure of the air-stable compd. [Zn(SeCH2CH2NMe2)2] (1), which was prepd. from Zn(OAc)2·2H2O and 2 equiv of NaSeCH2CH2NMe2 shows that the complex consists of monomeric mols. with a characteristically distorted tetrahedral zinc atom coordinated to two selenium and two nitrogen atoms. On thermolysis 1 yields ZnSe which was characterized by XRD. [on SciFinder(R)]

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